Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 27, Problem 29PP
(a)
Interpretation Introduction
Interpretation:
Identify the repeating unit of the polymer formed and classify as chain-growth or step-growth
Concept introduction:
- Polymers can be classified as chain-growth and step-growth polymers.
- Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time.
- This growing polymer chain usually has only one reactive site. This site is called growth point.
- Step-growth polymers are the one when the monomers react with each other to form oligomers.
- These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.
To identify: The polymer formed and to determine whether it is step-growth or chain-growth polymer.
(b)
Interpretation Introduction
Interpretation:
Identify the repeating unit of the polymer formed and classify as chain-growth or step-growth polymers.
Concept introduction:
- Polymers can be classified as chain-growth and step-growth polymers.
- Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time.
- This growing polymer chain usually has only one reactive site. This site is called growth point.
- Step-growth polymers are the one when the monomers react with each other to form oligomers.
- These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.
To identify: The polymer formed and to determine whether it is step-growth or chain-growth polymer.
(c)
Interpretation Introduction
Interpretation:
Identify the repeating unit of the polymer formed and classify as chain-growth or step-growth polymers.
Concept introduction:
- Polymers can be classified as chain-growth and step-growth polymers.
- Chain-growth polymers are the one which are formed when monomer is added to the other monomer growing chain one at a time.
- This growing polymer chain usually has only one reactive site. This site is called growth point.
- Step-growth polymers are the one when the monomers react with each other to form oligomers.
- These oligomers are joined together to form polymers. This usually occurs when difunctional monomers are used. This has got two growth points.
To identify: The polymer formed and to determine whether it is step-growth or chain-growth polymer.
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6. Consider the following exothermic reaction below.
2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq)
a. If Cul is added, there will be a shift left/shift right/no shift (circle one).
b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one).
c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one).
d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle
one). Hint: one of the reaction species is more soluble in hexane than in water.
e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one).
f. Which of the changes above will change the equilibrium constant, K?
Show work. don't give Ai
Show work with explanation needed. don't give Ai generated solution
Chapter 27 Solutions
Organic Chemistry, Binder Ready Version
Ch. 27.2 - Prob. 1CCCh. 27.2 - Prob. 2CCCh. 27.3 - Prob. 3CCCh. 27.3 - Prob. 4CCCh. 27.3 - Prob. 5CCCh. 27.4 - Prob. 1LTSCh. 27.4 - Prob. 6PTSCh. 27.4 - Prob. 7ATSCh. 27.4 - Prob. 8ATSCh. 27.4 - Prob. 9ATS
Ch. 27.4 - Prob. 10ATSCh. 27.4 - Prob. 11CCCh. 27.4 - Prob. 12CCCh. 27.4 - Prob. 2LTSCh. 27.4 - Prob. 13PTSCh. 27.4 - Prob. 14PTSCh. 27.4 - Prob. 15ATSCh. 27.4 - Prob. 16ATSCh. 27.5 - Prob. 17CCCh. 27.5 - Prob. 18CCCh. 27.6 - Prob. 19CCCh. 27.6 - Prob. 20CCCh. 27.8 - Prob. 21CCCh. 27 - Prob. 22PPCh. 27 - Prob. 23PPCh. 27 - Prob. 24PPCh. 27 - Prob. 25PPCh. 27 - Prob. 26PPCh. 27 - Prob. 27PPCh. 27 - Prob. 28PPCh. 27 - Prob. 29PPCh. 27 - Prob. 30PPCh. 27 - Prob. 31PPCh. 27 - Prob. 32PPCh. 27 - Prob. 33PPCh. 27 - Prob. 34PPCh. 27 - Prob. 35PPCh. 27 - Prob. 36PPCh. 27 - Prob. 37PPCh. 27 - Prob. 38PPCh. 27 - Prob. 39PPCh. 27 - Prob. 40PPCh. 27 - Prob. 41PPCh. 27 - Prob. 42PPCh. 27 - Prob. 43IPCh. 27 - Prob. 44IPCh. 27 - Prob. 45IPCh. 27 - Prob. 46CPCh. 27 - Prob. 47CPCh. 27 - Prob. 48CP
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