ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 27, Problem 28P
Interpretation Introduction

Interpretation:

A mechanism for the reaction of the glycosyl donor with the glycosyl acceptor in solid-phase synthesis of oligosaccharides is to be written. The regioselectivity of the given reaction is to be explained.

Concept Introduction:

The epoxidation of alkenes can be done by using DMDO.

The regioselectivity of epoxide ring opening reaction is determined by steric effects and the presence of electron withdrawing/donating groups attached to the epoxide carbon atoms.

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