ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 26.6, Problem 10P
Interpretation Introduction

Interpretation:

The standard amino acid that is the biological precursor to γ-butyric acid (4-aminobutanoic acid) which it forms by decarboxylation is to be determined.

Concept Introduction:

Standard amino acids are α-amino acids, that is they have the amine group bonded to the same carbon that is bonded to the carboxylic acid group.

Decarboxylation reaction replaces the COOH group by a hydrogen atom with evolution of the carbon dioxide.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer
curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps
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