(a) Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other. Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 1

Question

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer d, e, and f

If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1

Answer 2

Question

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 3

Question

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 4

Question

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 5

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 6

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 7

Chapter 26.4, Problem 9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 12

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 13

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 14

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 15

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 16

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 17

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constutitional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 26.2 - Prob. 1P Ch. 26.2 - Prob. 2P Ch. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5P Ch. 26.2 - Prob. 6P Ch. 26.3 - Prob. 7P Ch. 26.3 - Prob. 8P Ch. 26.4 - Prob. 9P Ch. 26.4 - Prob. 10P

Solution Summary: The author explains that D-allose and L-fructose are classified as epimers, but not as constutitional isomers.

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