The mechanism for branching in free radical polymerisation of styrene is to be shown and the type of aliphatic hydrogen which is most likely to be abstracted is to be explained. Concept Introduction: Free radical polymerisation is the polymerisation in which polymer forms through free radical mechanism in which electrons are equally distributed between both atoms involved in bonding. Styrene polymerises via free radical polymerisation in the presence of benzoyl peroxide. To determine: The mechanism of the given reaction; also the type of hydrogen which is most likely to be abstracted in the given reaction.

Question

None

Answer 1

Question

Definition Definition Monomer units that are not only combined in the linear chain but are also attached through branches of different lengths along the main chain. Branched-chain polymers have a lower density, lower melting point, and lower tensile strength compared to linear chain polymers because branched-chain does not pack well. Examples of branched-chain polymers are amylopectin and glycogen.

Chapter 26.2A, Problem 26.3P

Interpretation Introduction

Interpretation: The mechanism for branching in free radical polymerisation of styrene is to be shown and the type of aliphatic hydrogen which is most likely to be abstracted is to be explained.

Concept Introduction: Free radical polymerisation is the polymerisation in which polymer forms through free radical mechanism in which electrons are equally distributed between both atoms involved in bonding. Styrene polymerises via free radical polymerisation in the presence of benzoyl peroxide.

To determine: The mechanism of the given reaction; also the type of hydrogen which is most likely to be abstracted in the given reaction.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

None

Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

None

Answer 2

Question

Definition Definition Monomer units that are not only combined in the linear chain but are also attached through branches of different lengths along the main chain. Branched-chain polymers have a lower density, lower melting point, and lower tensile strength compared to linear chain polymers because branched-chain does not pack well. Examples of branched-chain polymers are amylopectin and glycogen.

Chapter 26.2A, Problem 26.3P

Interpretation Introduction

Interpretation: The mechanism for branching in free radical polymerisation of styrene is to be shown and the type of aliphatic hydrogen which is most likely to be abstracted is to be explained.

Concept Introduction: Free radical polymerisation is the polymerisation in which polymer forms through free radical mechanism in which electrons are equally distributed between both atoms involved in bonding. Styrene polymerises via free radical polymerisation in the presence of benzoyl peroxide.

To determine: The mechanism of the given reaction; also the type of hydrogen which is most likely to be abstracted in the given reaction.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Monomer units that are not only combined in the linear chain but are also attached through branches of different lengths along the main chain. Branched-chain polymers have a lower density, lower melting point, and lower tensile strength compared to linear chain polymers because branched-chain does not pack well. Examples of branched-chain polymers are amylopectin and glycogen.

Chapter 26.2A, Problem 26.3P

Interpretation Introduction

Interpretation: The mechanism for branching in free radical polymerisation of styrene is to be shown and the type of aliphatic hydrogen which is most likely to be abstracted is to be explained.

Concept Introduction: Free radical polymerisation is the polymerisation in which polymer forms through free radical mechanism in which electrons are equally distributed between both atoms involved in bonding. Styrene polymerises via free radical polymerisation in the presence of benzoyl peroxide.

To determine: The mechanism of the given reaction; also the type of hydrogen which is most likely to be abstracted in the given reaction.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Monomer units that are not only combined in the linear chain but are also attached through branches of different lengths along the main chain. Branched-chain polymers have a lower density, lower melting point, and lower tensile strength compared to linear chain polymers because branched-chain does not pack well. Examples of branched-chain polymers are amylopectin and glycogen.

Chapter 26.2A, Problem 26.3P

Interpretation Introduction