EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
Question
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Chapter 26, Problem 26.31SP

(a)

Interpretation Introduction

Interpretation:

The structures of poly (vinyl acetate) and poly (vinyl alcohol) are to be stated.

Concept introduction:

The poly (vinyl acetate) and poly (vinyl alcohol) are examples of addition polymers. These polymers are made, when some alkenes undergo chain growth polymerization by some initiator.

(b)

Interpretation Introduction

Interpretation:

An explanation to predict that the poly (vinyl acetate) is polyester as vinyl acetate is an ester is to be stated.

Concept introduction:

The poly (vinyl acetate) and poly (vinyl alcohol) are examples of addition polymers. These polymers are made, when some alkenes undergo chain growth polymerization by some initiator.

(c)

Interpretation Introduction

Interpretation:

An explanation corresponding to the given statement that hydrolysis does not destroy the poly (vinyl alcohol) polymer is to be stated.

Concept introduction:

The poly (vinyl acetate) and poly (vinyl alcohol) are examples of addition polymers. These polymers are made, when some alkenes undergo chain growth polymerization by some initiator.

(d)

Interpretation Introduction

Interpretation:

An explanation corresponding to the given statement that the poly (vinyl alcohol) is made by given circuitous route rather than the polymerisation of vinyl alcohol is to be stated.

Concept introduction:

The poly (vinyl acetate) and poly (vinyl alcohol) are examples of addition polymers. The poly (vinyl acetate) is converted to poly (vinyl alcohol) by a basic hydrolysis of the ester groups.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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