Connect Online Access 1-Semester for Organic Chemistry
Connect Online Access 1-Semester for Organic Chemistry
6th Edition
ISBN: 9781260475609
Author: SMITH, Janice
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 26.13, Problem 35P
Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that the two purine bases (A and G) cannot form a base pair and hydrogen bond to each other on two strands of DNA in the double helix is to be stated.

Concept introduction: The building block of DNA and RNA is nucleotide. There is a specific structure for each and every nucleotide which enables the formation of DNA and RNA. DNA is composed by the four nitrogenous bases. These are connected by the chemical bond.

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that the hydrogen bonding between guanine and cytosine is more favorable than hydrogen bonding between guanine and thymine is to be stated.

Concept introduction: The building block of DNA and RNA is nucleotide. It is an organic molecule. There is a specific structure for each and every nucleotide which enables the formation of DNA and RNA. DNA is composed by the four nitrogenous bases. These are connected by the chemical bond.

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CH3 CH H3C CH3 H OH H3C- -OCH2CH3 H3C H -OCH3 For each of the above compounds, do the following: 1. List the wave numbers of all the IR bands in the 1350-4000 cm-1 region. For each one, state what bond or group it represents. 2. Label equivalent sets of protons with lower-case letters. Then, for each 1H NMR signal, give the 8 value, the type of splitting (singlet, doublet etc.), and the number protons it represents. of letter δ value splitting # of protons 3. Redraw the compound and label equivalent sets of carbons with lower-case letters. Then for each set of carbons give the 5 value and # of carbons it represents. letter δ value # of carbons
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Chapter 26 Solutions

Connect Online Access 1-Semester for Organic Chemistry

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