ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
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Chapter 26, Problem 54IP

(a)

Interpretation Introduction

Interpretation:

Conversion of oleic acid into the given set of compounds is done by reagents and the same has to be identified.

Concept introduction:

Hydrogenation is a reaction where hydrogen is added to a compound to get the product in the reduced form.  Few examples are, unsaturated compounds are converted to saturated compounds,  ketone to alcohol, carboxylic acid to alcohol etc.

To identify: the reagents used for transformation of oleic acid into stearic acid.

(b)

Interpretation Introduction

Interpretation:

Conversion of oleic acid into the given set of compounds is done by reagents and the same has to be identified.

Concept introduction:

Hydrogenation is a reaction where hydrogen is added to a compound to get the product in the reduced form.  Few examples are, unsaturated compounds are converted to saturated compounds,  ketone to alcohol, carboxylic acid to alcohol etc.

Esterification is a reaction in which a carboxylic acid and an alcohol is reacted in presence of aqueous acid or base to form a ester bond.

To identify: the reagents used for conversion of oleic acid to ethyl stearate.

(c)

Interpretation Introduction

Interpretation:

Conversion of oleic acid into the given set of compounds is done by reagents and the same has to be identified.

Concept introduction:

Hydrogenation is a reaction where hydrogen is added to a compound to get the product in the reduced form.  Few examples are, unsaturated compounds are converted to saturated compounds,  ketone to alcohol, carboxylic acid to alcohol etc.

Carboxylic acid to alcohol requires a strong reducing agent such as LAH .

To identify: the reagents used for conversion of oleic acid to 1-octadecanol.

(d)

Interpretation Introduction

Interpretation:

Conversion of oleic acid into the given set of compounds is done by reagents and the same has to be identified.

Concept introduction:

Ozonolysis of the an alkene by use of ozone yields two aldehyde.

Aldehyde when undergoes oxidation using a strong oxidizing agent gives carboxylic acid as the product.

To identify: the reagents used for conversion of oleic acid to nonanedioic acid.

(e)

Interpretation Introduction

Interpretation:

Conversion of oleic acid into the given set of compounds is done by reagents and the same has to be identified.

Concept introduction:

Hydrogenation is a reaction where hydrogen is added to a compound to get the product in the reduced form.  Few examples are, unsaturated compounds are converted to saturated compounds,  ketone to alcohol, carboxylic acid to alcohol etc.

Bromination of the α -carbon is done using the bromine and phosphorous tribromide.

To identify: the reagents used for conversion of oleic acid to 2-bromostearic acid.

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21. Zn Cl₂→ ZnCl2 22. ZnCO3 ZnO CO₂ 23. Mg + Sg MgS 24. Fe + Cl₂ FeCl3 25. Ag + S8 Ag₂S 26. K S8 K₂S 27. Al HCI AlCl3 H2 28. Mg H3PO4 Mg3(PO4)2 + H₂ 29. Cu + AgNO3 Cu(NO3)2 + Ag 30. Al + Pb(NO3)2 Pb + Al(NO3)3 31. Zn + Sn(NO3)4 Zn(NO3)2 Sn 32. Cl2 + All 3 AlCl3 _ 12 33. Br2 + Cul CuBr 12 34. KBr + Pb(NO3)2 KNO3 PbBr2 These next ones have an element shared between two different compounds. The Total amount in the Reactatnt still needs to equal the total amount in the product. 35.H₂O2 ← H₂O + 0₂ 36. C₂Ho CO2 + H₂O 37. Zn + HCI → ZnCl+ H₂ 38. NH3 + _HCl → NH.C 39. Mg(OH)2 + H3PO4 → H₂O+ Mg3(PO4)2 40. NHẠOH + FeCl3 NH4Cl + Fe(OH)3
Don't used hand raiting and don't used Ai solution
Balance the following equations Synthesis Ca 1. Mg + Cl₂ → MgCl2Syn 2. Al + 302 -> 2A1203Com 3. P4 + 502 4. Bi + + Cl₂ 5. H2 + N2 ↑ 6. Zn + 02 7. Cu + 02 8. Sn + 9. Na 10. 11. AR Ag + Cl₂ S8 I2 ↑ ↑ ↑ ↑ Pb + 12. Al + Br₂ 13. Fe + F2 ↑ 14. Sn + 15. Sb + 16. Ca + 17. Ba + 02 ↑ ↑ ↑ P4010 Com BiCl, Syn NH3 Syn Zno Com Cu2O com SnCl4 Syn Na2S Syn Agl Syn Pbo Com AlBr, yn FeF3 Syn Sno com Sb₂Ss Syn Cao cơm Bao cơm 18. Mg + P4 -> Mg3P2 Syn 19. K + K&N Syn ZnS Syn 20. Zn
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