ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 26, Problem 50DSP
Interpretation Introduction

Interpretation:

The carbon atom of L-glutamic acid, which is involved in the only carbon-carbon bond forming step of the synthesis given, is to be determined.

Concept introduction:

Natural L-glutamic acid has S configuration. If no reaction takes places at the chiral carbon atom of the amino acid, then its configuration is retained in the products formed.

The alpha carbon atom in the amino acid is attached to a nitrogen atom, the carboxyl carbon, and one other carbon atom.

Tracing the carbon atoms of the amino acid in the product, the carbon atoms of the amino acid in the product can be identified.

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424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)
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