ORGANIC CHEMISTRY PRINCIPLES & MECHANISM
ORGANIC CHEMISTRY PRINCIPLES & MECHANISM
2nd Edition
ISBN: 9780393681826
Author: KARTY
Publisher: NORTON
Question
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Chapter 26, Problem 26.73P
Interpretation Introduction

(a)

Interpretation:

Dry-erase boards, or whiteboards, in classrooms, consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. A structure of the polymer formed is to be drawn.

Concept introduction:

The anime ( -NH2 ) group is nucleophilic towards the carbonyl carbon, when it is treated with an aldehyde, in presence of acid as the catalyst, corresponding primary alcohol will be formed. The melamine also possesses -NH2 a group and reacts with an aldehyde to form the corresponding alcohol in the presence of acid. In acidic conditions alcoholic group also eliminated in the form of water and generates carbocation.

Interpretation Introduction

(b)

Interpretation:

Dry-erase boards, or whiteboards, in classrooms, consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. It is to be explained why this polymer suitable for use in whiteboards.

Concept introduction:

The anime ( -NH2 ) group is nucleophilic towards the carbonyl carbon, when it is treated with an aldehyde, in presence of acid as the catalyst, corresponding primary alcohol will be formed. The melamine also possesses -NH2 a group and reacts with an aldehyde to form the corresponding alcohol in the presence of acid. In acidic conditions alcoholic group also eliminated in the form of water and generates carbocation. Network polymers are insoluble in most of organic as well as inorganic solvents.

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Chapter 26 Solutions

ORGANIC CHEMISTRY PRINCIPLES & MECHANISM

Ch. 26 - Prob. 26.11PCh. 26 - Prob. 26.12PCh. 26 - Prob. 26.13PCh. 26 - Prob. 26.14PCh. 26 - Prob. 26.15PCh. 26 - Prob. 26.16PCh. 26 - Prob. 26.17PCh. 26 - Prob. 26.18PCh. 26 - Prob. 26.19PCh. 26 - Prob. 26.20PCh. 26 - Prob. 26.21PCh. 26 - Prob. 26.22PCh. 26 - Prob. 26.23PCh. 26 - Prob. 26.24PCh. 26 - Prob. 26.25PCh. 26 - Prob. 26.26PCh. 26 - Prob. 26.27PCh. 26 - Prob. 26.28PCh. 26 - Prob. 26.29PCh. 26 - Prob. 26.30PCh. 26 - Prob. 26.31PCh. 26 - Prob. 26.32PCh. 26 - Prob. 26.33PCh. 26 - Prob. 26.34PCh. 26 - Prob. 26.35PCh. 26 - Prob. 26.36PCh. 26 - Prob. 26.37PCh. 26 - Prob. 26.38PCh. 26 - Prob. 26.39PCh. 26 - Prob. 26.40PCh. 26 - Prob. 26.41PCh. 26 - Prob. 26.42PCh. 26 - Prob. 26.43PCh. 26 - Prob. 26.44PCh. 26 - Prob. 26.45PCh. 26 - Prob. 26.46PCh. 26 - Prob. 26.47PCh. 26 - Prob. 26.48PCh. 26 - Prob. 26.49PCh. 26 - Prob. 26.50PCh. 26 - Prob. 26.51PCh. 26 - Prob. 26.52PCh. 26 - Prob. 26.53PCh. 26 - Prob. 26.54PCh. 26 - Prob. 26.55PCh. 26 - Prob. 26.56PCh. 26 - Prob. 26.57PCh. 26 - Prob. 26.58PCh. 26 - Prob. 26.59PCh. 26 - Prob. 26.60PCh. 26 - Prob. 26.61PCh. 26 - Prob. 26.62PCh. 26 - Prob. 26.63PCh. 26 - Prob. 26.64PCh. 26 - Prob. 26.65PCh. 26 - Prob. 26.66PCh. 26 - Prob. 26.67PCh. 26 - Prob. 26.68PCh. 26 - Prob. 26.69PCh. 26 - Prob. 26.70PCh. 26 - Prob. 26.71PCh. 26 - Prob. 26.72PCh. 26 - Prob. 26.73PCh. 26 - Prob. 26.74PCh. 26 - Prob. 26.75PCh. 26 - Prob. 26.76PCh. 26 - Prob. 26.77PCh. 26 - Prob. 26.78PCh. 26 - Prob. 26.1YTCh. 26 - Prob. 26.2YTCh. 26 - Prob. 26.3YTCh. 26 - Prob. 26.4YTCh. 26 - Prob. 26.5YTCh. 26 - Prob. 26.6YTCh. 26 - Prob. 26.7YTCh. 26 - Prob. 26.8YTCh. 26 - Prob. 26.9YTCh. 26 - Prob. 26.10YTCh. 26 - Prob. 26.11YTCh. 26 - Prob. 26.12YTCh. 26 - Prob. 26.13YTCh. 26 - Prob. 26.14YTCh. 26 - Prob. 26.15YTCh. 26 - Prob. 26.16YTCh. 26 - Prob. 26.17YTCh. 26 - Prob. 26.18YTCh. 26 - Prob. 26.19YTCh. 26 - Prob. 26.20YTCh. 26 - Prob. 26.21YTCh. 26 - Prob. 26.22YTCh. 26 - Prob. 26.23YT
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