General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 26, Problem 26.10P
Interpretation Introduction
Interpretation:
Basic oxygen process has to be described.
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reducing a monosaccharide
a non reducing disaccharide
amylopectin
cellulose
1,4' beta- glycoside
Refer to the monosaccharides below to answer each of the following questions:
CH2OH
CHO
CH₂OH
CHZOH
0
H
OH
0
0
HO
H
H
OH
HO
H
HO
H
H
OH
HO
H
CHZOH
H
OH
HO
H
HO
H
CHZOH
CHZOH
CH3
a Sorbose
b. Rhamnose
c. Erythrulose
d. Xylulose
Classify each sugar by type; for example, glucose is an aldohexose.
A. Xylulose is
B. Erythrulose is
C. Sorbose is
D.
Rhamnose is
Refer to the sugars below to answer the following questions. Choose the sugar that best fits each
escription and place the letter of the sugar in the blank to the left of the description. There is only one
orrect answer for each question, but sugars may be used more than once.
CH₂OH
0
CHO
HO
H
CHO
CH₂OH
HO
H
HO
H
HO
H
H
OH
HH
OH
OH
H
OH
H
OH
HO
H
CH₂OH
H
OH
CH₂OH
CH₂OH
CH₂OH
a (-)-tagatose
b. (+) gulose
c. (-)-erythrose
d (-)-n bulos
A.
ARCD
a D-ketohexose
B.
C.
D.
oxidizes to an optically inactive aldaric acid
a dextrorotary hexose
a ketose with two chirality centers
Chapter 26 Solutions
General Chemistry
Ch. 26 - Prob. 26.1PCh. 26 - Prob. 26.2PCh. 26 - Prob. 26.3PCh. 26 - Prob. 26.4PCh. 26 - Prob. 26.5PCh. 26 - Prob. 26.6PCh. 26 - Prob. 26.7PCh. 26 - Prob. 26.8PCh. 26 - Prob. 26.9PCh. 26 - Prob. 26.10P
Ch. 26 - Prob. 26.11PCh. 26 - Prob. 26.12PCh. 26 - Prob. 26.13PCh. 26 - Prob. 26.14PCh. 26 - Prob. 26.15PCh. 26 - Prob. 26.16PCh. 26 - Prob. 26.17PCh. 26 - Prob. 26.18PCh. 26 - Prob. 26.19PCh. 26 - Prob. 26.20PCh. 26 - Prob. 26.21PCh. 26 - Prob. 26.22PCh. 26 - Prob. 26.23PCh. 26 - Prob. 26.24PCh. 26 - Prob. 26.25PCh. 26 - Prob. 26.26PCh. 26 - Prob. 26.27PCh. 26 - Prob. 26.28PCh. 26 - Prob. 26.29PCh. 26 - Prob. 26.30PCh. 26 - Prob. 26.31PCh. 26 - Prob. 26.32PCh. 26 - Prob. 26.33PCh. 26 - Prob. 26.34PCh. 26 - Prob. 26.35PCh. 26 - Prob. 26.36PCh. 26 - Prob. 26.37PCh. 26 - Prob. 26.38PCh. 26 - Prob. 26.39PCh. 26 - Prob. 26.40PCh. 26 - Prob. 26.41PCh. 26 - Prob. 26.42PCh. 26 - Prob. 26.43PCh. 26 - Prob. 26.44PCh. 26 - Prob. 26.45PCh. 26 - Prob. 26.46PCh. 26 - Prob. 26.47PCh. 26 - Prob. 26.48PCh. 26 - Prob. 26.49PCh. 26 - Prob. 26.50PCh. 26 - Prob. 26.51PCh. 26 - Prob. 26.52PCh. 26 - Prob. 26.53PCh. 26 - Prob. 26.54PCh. 26 - Prob. 26.55PCh. 26 - Prob. 26.56PCh. 26 - Prob. 26.57PCh. 26 - Prob. 26.58PCh. 26 - Prob. 26.59PCh. 26 - Prob. 26.61PCh. 26 - Prob. 26.62PCh. 26 - Prob. 26.63PCh. 26 - Prob. 26.64PCh. 26 - Prob. 26.65PCh. 26 - Prob. 26.66PCh. 26 - Prob. 26.67PCh. 26 - Prob. 26.68PCh. 26 - Prob. 26.69PCh. 26 - Prob. 26.70P
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- Show how each of the following transformations might be best accomplished. More than one step may required. Show all reagents and all intermediate structures. [4 only] CH3 A. CH CH2 C Br CH3 CH3 CH3CH2 C NH2 CH3 B OH any source of carbon N MIHarrow_forwardConsider the reaction below to answer the following questions. 0 0 25 PS ES 1919sds-III msx H H + 5% NaOCH 3, CH3OHA O CH₂OH Jeiniog 2E1 gniwool of mor]. Ignibuloni 9vil 19 A B 11 >buoqm gniwollol so dass 101 tomboy boo-11Coble or to r ton auch i viw ninlaxs, noitsausbroo 152 lobla ogsbau ton 250b br A. Which carbonyl compound functions as the electrophile in this reaction? B. Draw the structure of the enolate ion that is generated during the course of this reaction. C. This reaction is an example of: a. a mixed Claisen condensation. b. C. d. a Dieckman condensation. a Michael reaction. a mixed aldol reaction. HD HDarrow_forwardConsider the reaction below to answer the following questions: 847 Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate. H₁C 0 H 0 IL 유 || OCH2CH3 1. NaOEt, EtOH C 2. H₂O H3C CH₂ Cold not tobizmo. S OCH2CH3 A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and draw all intermediate structures. B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents and structures for all intermediates in this preparation. C. Give the structures of the ester precursors for the following Claisen condensation product and formulate the reaction. ou OELarrow_forward
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