EBK GENERAL CHEMISTRY
11th Edition
ISBN: 9780133400588
Author: Bissonnette
Publisher: VST
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Chapter 26, Problem 13E
Identify the chiral carbon atoms, ¡f any, in the following compounds.
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Chapter 26 Solutions
EBK GENERAL CHEMISTRY
Ch. 26 - Prob. 1ECh. 26 - Draw a structural formula for each of the...Ch. 26 - Prob. 3ECh. 26 - Write structural formulas corresponding to these...Ch. 26 - Prob. 5ECh. 26 - Prob. 6ECh. 26 - Prob. 7ECh. 26 - Prob. 8ECh. 26 - What is the relationship, if any, between the...Ch. 26 - Prob. 10E
Ch. 26 - Prob. 11ECh. 26 - Prob. 12ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 14ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 16ECh. 26 - Prob. 17ECh. 26 - Prob. 18ECh. 26 - Prob. 19ECh. 26 - By name or formula, give one example of each of...Ch. 26 - Prob. 21ECh. 26 - Prob. 22ECh. 26 - Prob. 23ECh. 26 - Prob. 24ECh. 26 - Prob. 25ECh. 26 - Prob. 26ECh. 26 - Prob. 27ECh. 26 - Prob. 28ECh. 26 - Prob. 29ECh. 26 - Prob. 30ECh. 26 - Prob. 31ECh. 26 - Prob. 32ECh. 26 - Prob. 33ECh. 26 - Prob. 34ECh. 26 - Does each of the following names convey sufficient...Ch. 26 - Prob. 36ECh. 26 - Prob. 37ECh. 26 - Supply condensed structural formulas for the...Ch. 26 - Prob. 39ECh. 26 - Prob. 40ECh. 26 - Classify the carbon atoms in, a. methylbutane, and...Ch. 26 - Classity the carbon atoms in a....Ch. 26 - Prob. 43ECh. 26 - Draw Newman projections for the staggered and...Ch. 26 - Draw the most stable conformation for the molecule...Ch. 26 - Prob. 46ECh. 26 - Prob. 47ECh. 26 - Prob. 48ECh. 26 - Prob. 49ECh. 26 - Prob. 50ECh. 26 - Prob. 51ECh. 26 - Prob. 52ECh. 26 - Prob. 53ECh. 26 - Prob. 54ECh. 26 - Prob. 55ECh. 26 - Prob. 56ECh. 26 - Draw suitable structural formulas to show that...Ch. 26 - Which of the following pairs of molecules are...Ch. 26 - Prob. 59ECh. 26 - Prob. 60ECh. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Prob. 64ECh. 26 - Draw the structure for each of the following. a....Ch. 26 - Prob. 66ECh. 26 - Prob. 67ECh. 26 - Prob. 68ECh. 26 - Prob. 69ECh. 26 - Prob. 70ECh. 26 - Prob. 71ECh. 26 - Prob. 72ECh. 26 - Prob. 73ECh. 26 - Prob. 74ECh. 26 - Supply condensed or structural formulas for the...Ch. 26 - Prob. 76IAECh. 26 - Prob. 77IAECh. 26 - Prob. 78IAECh. 26 - Prob. 79IAECh. 26 - Prob. 80IAECh. 26 - Combustion of a 0.1908 g sample of a compound gave...Ch. 26 - Prob. 82IAECh. 26 - In the monochiorination of hydrocarbons, a...Ch. 26 - A particular colorless organic liquid is known to...Ch. 26 - Prob. 85IAECh. 26 - Give the systematic names, including any...Ch. 26 - Prob. 87IAECh. 26 - Prob. 88IAECh. 26 - Levomethadyl acetate (shown below) is used in the...Ch. 26 - Thiamphenicol (shown below) is an antibacterial...Ch. 26 - Prob. 91IAECh. 26 - Prob. 92IAECh. 26 - Prob. 93IAECh. 26 - Prob. 94IAECh. 26 - Prob. 95IAECh. 26 - For each of the following molecules (a) draw the...Ch. 26 - Prob. 97FPCh. 26 - Prob. 98SAECh. 26 - Explain the important distinctions between each...Ch. 26 - Describe the characteristics of each of the...Ch. 26 - The compound isoheptane is best represented by the...Ch. 26 - Prob. 102SAECh. 26 - Prob. 103SAECh. 26 - Prob. 104SAECh. 26 - Assign configurations, R or S, to the chiral...Ch. 26 - Consider the following pairs of structures In each...Ch. 26 - Prob. 107SAECh. 26 - Prob. 108SAECh. 26 - Prob. 109SAECh. 26 - Prob. 110SAECh. 26 - Prob. 111SAE
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