ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN
ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN
4th Edition
ISBN: 9781119760924
Author: Klein
Publisher: WILEY
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Chapter 25.6, Problem 34PTS

(a)

Interpretation Introduction

Interpretation:

Synthesis of given set of dipeptides must be drawn with the reagents.

Concept introduction:

Peptides are a chain of amino acids that are linked together by amide bond.  The key steps involved in peptide synthesis is,

  • Installation of appropriate protecting groups in amino acid
  • Coupling of protected amino acids using DCC
  • Deprotection of protecting groups to give the final peptide.

To draw : To draw all steps and reagents for the synthesis of dipeptide Trp-Met

(b)

Interpretation Introduction

Interpretation:

Synthesis of given set of dipeptides must be drawn with the reagents.

Concept introduction:

Peptides are a chain of amino acids that are linked together by amide bond.  The key steps involved in peptide synthesis is,

  • Installation of appropriate protecting groups in amino acid
  • Coupling of protected amino acids using DCC
  • Deprotection of protecting groups to give the final peptide.

To draw : To draw all steps and reagents for the synthesis of dipeptide Ala-Ile

(c)

Interpretation Introduction

Interpretation:

Synthesis of given set of dipeptides must be drawn with the reagents.

Concept introduction:

Peptides are a chain of amino acids that are linked together by amide bond.  The key steps involved in peptide synthesis is,

  • Installation of appropriate protecting groups in amino acid
  • Coupling of protected amino acids using DCC
  • Deprotection of protecting groups to give the final peptide.

To draw : To draw all steps and reagents for the synthesis of dipeptide Leu-Val

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Explanation O Conjugated Pi Systems Deducing the reactants of a Diels-Alder reaction Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? Δ If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. • If your answer is no, check the box under the drawing area instead. Click and drag to start drawing a structure. X
Diels Alder Cycloaddition: Focus on regiochemistry (problems E-F) –> match + of thedienophile and - of the diene while also considering stereochemistry (endo).
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Chapter 25 Solutions

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