ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN
ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN
4th Edition
ISBN: 9781119760924
Author: Klein
Publisher: WILEY
Question
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Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN, Chapter 25.3, Problem 12CC , additional homework tip  1

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN, Chapter 25.3, Problem 12CC , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN, Chapter 25.3, Problem 12CC , additional homework tip  3

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN, Chapter 25.3, Problem 12CC , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN, Chapter 25.3, Problem 12CC , additional homework tip  5

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

ORGANIC CHEMISTRY-WILEYPLUS NEXTGEN, Chapter 25.3, Problem 12CC , additional homework tip  6

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