EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
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Chapter 25.5, Problem 25.8P
Interpretation Introduction
Interpretation: An explanation to show that the phosphatidic acid is chiral, even though none of its fatty acids are chiral is to be stated and identification of asymmetric carbon in phosphatidic acid is to be done.
Concept introduction: A carbon atom, linked to four different
To determine: An explanation to show that the phosphatidic acid is chiral, even though none of its fatty acids are chiral and identification of asymmetric carbon in phosphatidic acid.
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Chapter 25 Solutions
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
Ch. 25.3 - Prob. 25.1PCh. 25.3A - Prob. 25.2PCh. 25.3B - Give an equaton for the complete transestenfcation...Ch. 25.4 - Prob. 25.4PCh. 25.4 - Several commercial laundry soaps contain...Ch. 25.4 - Prob. 25.6PCh. 25.4 - Prob. 25.7PCh. 25.5 - Prob. 25.8PCh. 25.6 - How would you use a simple extraction to separate...Ch. 25.6 - Prob. 25.10P
Ch. 25.8A - Circle the isoprene units in geranial, menthol,...Ch. 25.8B - Prob. 25.12PCh. 25.8B - Prob. 25.13PCh. 25 - Prob. 25.14SPCh. 25 - Prob. 25.15SPCh. 25 - Show how you would convert oleic acid to the...Ch. 25 - Give the general classification of each compound....Ch. 25 - Phospholipids undergo saponification much like...Ch. 25 - Prob. 25.19SPCh. 25 - Prob. 25.20SPCh. 25 - Prob. 25.21SPCh. 25 - Prob. 25.22SPCh. 25 - Prob. 25.23SPCh. 25 - The structure of limonene appears in Problem25-13....Ch. 25 - Prob. 25.25SPCh. 25 - Prob. 25.26SPCh. 25 - Prob. 25.27SPCh. 25 - Prob. 25.28SPCh. 25 - Prob. 25.29SPCh. 25 - Prob. 25.30SPCh. 25 - Prob. 25.31SPCh. 25 - Prob. 25.32SP
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- It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]arrow_forward206 Pb 82 Express your answers as integers. Enter your answers separated by a comma. ▸ View Available Hint(s) VAΣ ΜΕ ΑΣΦ Np, N₁ = 82,126 Submit Previous Answers ? protons, neutronsarrow_forwardPlease draw the inverted chair forms of the products for the two equilibrium reactions shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No requirement to show or do calculations.] CH3 CH3 HH CH3 1 -CH3arrow_forward
- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
- 32S 16 Enter your answers numerically separated by a comma. Np. Nn = 跖 ΟΙ ΑΣΦ Submit Request Answer ? protons, neutronsarrow_forward2. Which dimethylcyclohexane compounds shown below exhibit symmetry and therefore are not chiral and would not rotate plane polarized light. 1 CH3 CH CH3 CH3 2 3 CH3arrow_forwardDon't used hand raitingarrow_forward
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