Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Chapter 25.4, Problem 25.7P
Interpretation Introduction

Interpretation: An aromatic substitution reaction to show the path for the conversion of pentamer to the final synthetic detergent is to be stated.

Concept introduction: Hydrogen gas in the presence of Ni metal catalyst is used to reduce unsaturated hydrocarbon to saturated hydrocarbon. The Fridel-crafts alkylation comprises the alkylation of aromatic ring in the presence of Lewis acid catalyst. Concentrated H2SO4 is used for sulfonation of aromatic compound. This reaction is an example of electrophilic aromatic substitution reaction. NaOH/H2O is used to convert sulfonic group into sodium salt of sulfonate.

To determine: An aromatic substitution reaction to show the path for the conversion of pentamer to the final synthetic detergent.

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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!
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