(a)
Interpretation:
Bond-line structure of given set of peptides need to be drawn.
Concept introduction:
Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,
- Draw the peptide with correct number of residues
- The side chain associated with the residue has to be identified
- Assign proper configuration for the residues
To draw: bond-line structure of peptide Leu-Ala-Gly
(b)
Interpretation:
Bond-line structure of given set of peptides need to be drawn.
Concept introduction:
Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,
- Draw the peptide with correct number of residues
- The side chain associated with the residue has to be identified
- Assign proper configuration for the residues
To draw: bond-line structure of peptide Cys-Asp-Ala-Gly
(c)
Interpretation:
Bond-line structure of given set of peptides need to be drawn.
Concept introduction:
Bond-line structure is the representation of organic structural formulas in a shorthand manner. In this case only the bond between carbon and other atoms are shown except hydrogen. It is understood that all the remaining valency to be filled by hydrogen. Apart from carbon atoms the other atoms are shown along with hydrogen. For drawing a peptide sequence in bond-line structure the steps need to be followed are,
- Draw the peptide with correct number of residues
- The side chain associated with the residue has to be identified
- Assign proper configuration for the residues
To draw: bond-line structure of peptide Met-Lys-His-Tyr-Ser-Phe-Val
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Chapter 25 Solutions
ORGANIC CHEMISTRY-PRINT MULTI TERM
- 2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11arrow_forwardComplete the spectroscopy with structurearrow_forwardComplete the spectroscopy with structurearrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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