Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified. Concept introduction: Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below, Steps involved in amidomalonater synthesis are, Deprotonation of α carbon in amidomalonate Alkylation of enolate Hydrolysis of ester using aqueous acid Decarboxylation at high temperature To find : the reagents used for synthesis of isoleucine by amidomalonate synthesis.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

lighting discharges in the atmosphere catalyze the conversion of nitrogen to nitric oxide. How many grams of nitrogen would be required to make 25.0 g of nitric oxide in this way ?

The electron of a hydrogen atom is excited to the 4d orbital. Calculate the energy of the emitted photon if the electron were to move to each of the following orbitals: (a) 1s; (b) 2p; (c) 2s; (d) 4s. (e) Suppose the outermost electron of a potassium atom were excited to a 4d orbital and then moved to each of these same orbitals. Describe qualitatively the differences that would be found between the emission spectra of potassium and hydrogen (do not perform calculations). Explain your answer.

Imagine a four-dimensional world. In it, atoms would have one s orbital and four p orbitals in a given shell. (a) Describe the shape of the Periodic Table of the first 24 elements. (b) What elements would be the first two noble gases (use the names from our world that correspond to the atomic numbers).

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Answer 6

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

Answer 7

Chapter 25.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of isoleucine by amidomalonate synthesis.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of alanine by amidomalonate synthesis.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Reagents required for preparation of isoleucine, alanine and valine by using amidomalonate synthesis need to be identified.

Concept introduction:

Amidomalonate synthesis is a process in which an halide is converted to a aminoacid with two new carbon atoms (comes from amidomalonate). By use of this method a new alkyl groups can be introduced. A general scheme of this synthesis is shown below,

Steps involved in amidomalonater synthesis are,

Deprotonation of α carbon in amidomalonate

Alkylation of enolate

Hydrolysis of ester using aqueous acid

Decarboxylation at high temperature

To find: the reagents used for synthesis of valine by amidomalonate synthesis.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 25.2 - Prob. 1CC Ch. 25.2 - Prob. 2CC Ch. 25.2 - Prob. 3CC Ch. 25.2 - Prob. 1LTS Ch. 25.2 - Prob. 4PTS Ch. 25.2 - Prob. 7CC Ch. 25.2 - Prob. 8CC Ch. 25.2 - Prob. 9CC Ch. 25.2 - Prob. 10CC Ch. 25.2 - Prob. 11CC

Want to see the full answer?

Chapter 25 Solutions