General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 25.3, Problem 25.1PP
Interpretation Introduction
Interpretation:
Whether the environment represented by B in the figure is lungs or tissues needs to be determined.
Concept Introduction:
The blood carries oxygen to the whole body from the lungs, and it takes in carbon dioxide from the rest of the body to the lungs.
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 25 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 25.1 - Prob. 25.1PCh. 25.1 - Prob. 25.2PCh. 25.2 - Compare erythrocytes, leukocytes, and platelets...Ch. 25.2 - Prob. 25.4PCh. 25.2 - Prob. 25.5PCh. 25.2 - Prob. 25.6PCh. 25.2 - Prob. 25.7PCh. 25.3 - Prob. 25.8PCh. 25.3 - Prob. 25.1PPCh. 25.3 - Prob. 25.9P
Ch. 25.3 - Prob. 25.10PCh. 25.4 - Prob. 25.11PCh. 25.4 - Prob. 25.12PCh. 25.5 - (a) Which compound, morphine or heroin, is more...Ch. 25.5 - Prob. 25.14PCh. 25.6 - Prob. 25.15PCh. 25.6 - Prob. 25.16PCh. 25.6 - Prob. 25.17PCh. 25.6 - Individuals with a rare condition called diabetes...Ch. 25 - Prob. 19PCh. 25 - Prob. 20PCh. 25 - Prob. 21PCh. 25 - Prob. 22PCh. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - For each substance, indicate if it is present in...Ch. 25 - Prob. 28PCh. 25 - Prob. 29PCh. 25 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - Prob. 33PCh. 25 - Prob. 34PCh. 25 - Prob. 35PCh. 25 - Which of the following locations corresponds to...Ch. 25 - Prob. 37PCh. 25 - Prob. 38PCh. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Prob. 41PCh. 25 - Prob. 42PCh. 25 - Explain how abnormally fast respirationthat is,...Ch. 25 - Prob. 44PCh. 25 - Prob. 45PCh. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Prob. 48PCh. 25 - When blood flows through the glomerulus, which...Ch. 25 - Prob. 50PCh. 25 - Prob. 51PCh. 25 - Prob. 52P
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