The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified. Concept introduction: α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product. To identify : the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

C. NaOMe, Br Br

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Expert Solution & Answer

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See solution

Answer 5

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Answer 6

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

Answer 7

Chapter 25.3, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of leucine using Hell-Volhard-Zelinsky reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of alanine using Hell-Volhard-Zelinsky reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reagents for making the given amino acids using Hell-Volhard-Zelinsky reaction need to be identified.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction. The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

To identify: the reagents used for synthesis of valine using Hell-Volhard-Zelinsky reaction.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 25.2 - Prob. 1CC Ch. 25.2 - Prob. 2CC Ch. 25.2 - Prob. 3CC Ch. 25.2 - Prob. 1LTS Ch. 25.2 - Prob. 4PTS Ch. 25.2 - Prob. 7CC Ch. 25.2 - Prob. 8CC Ch. 25.2 - Prob. 9CC Ch. 25.2 - Prob. 10CC Ch. 25.2 - Prob. 11CC

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