Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 25, Problem 72P
Interpretation Introduction
Interpretation :
The reason for considering selenocysteine as 21st amino acid must be explained. The reason for excluding hydroxyproline and hydroxylysine from the list of amino acids must also be explained.
Concept Introduction :
Selenocysteine is a molecule in which there is selenium in place of sulfur. Additionally it contains one
Proline is known as an imino acid as it contains cyclic secondary
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 25 Solutions
Introduction to General, Organic and Biochemistry
Ch. 25.1 - Prob. 25.1QCCh. 25.2 - Problem 26-1 DNA is highly condensed in the...Ch. 25.3 - Prob. 25.3QCCh. 25.4 - Prob. 25.4QCCh. 25.5 - Prob. 25.5QCCh. 25.6 - Prob. 25.6QCCh. 25.7 - Prob. 25.7QCCh. 25.8 - Prob. 25.8QCCh. 25.9 - Prob. 25.9QCCh. 25 - Does the term gene expression refer to: (a)...
Ch. 25 - Prob. 2PCh. 25 - Where does most Of the translation occur in a...Ch. 25 - Prob. 4PCh. 25 - Prob. 5PCh. 25 - Prob. 6PCh. 25 - Prob. 7PCh. 25 - What is the function of RNA polymerase?Ch. 25 - What is the role of helicase in transcription?Ch. 25 - Prob. 10PCh. 25 - Prob. 11PCh. 25 - Prob. 12PCh. 25 - Prob. 13PCh. 25 - Prob. 14PCh. 25 - Prob. 15PCh. 25 - What are the different names used for the two...Ch. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Prob. 20PCh. 25 - Where are the codons located?Ch. 25 - What are the two most important sites on tRNA...Ch. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - (a) If a codon is GCU, what is the anticodon? (b)...Ch. 25 - If a segment of DNA is 981 units long, how many...Ch. 25 - In what sense does the universality of the genetic...Ch. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - A genetic code in which two bases encode a single...Ch. 25 - What is meant by the genetic code being continuous...Ch. 25 - Prob. 35PCh. 25 - Prob. 36PCh. 25 - Prob. 37PCh. 25 - Prob. 38PCh. 25 - Prob. 39PCh. 25 - What are the stages of protein synthesis?Ch. 25 - Prob. 41PCh. 25 - Explain what happens to the fMet initially put at...Ch. 25 - Prob. 43PCh. 25 - Why is amino acid activation called the second...Ch. 25 - Prob. 45PCh. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Prob. 48PCh. 25 - Prob. 49PCh. 25 - What kind of interactions exist between metal-...Ch. 25 - Prob. 51PCh. 25 - Prob. 52PCh. 25 - Prob. 53PCh. 25 - Prob. 54PCh. 25 - Prob. 55PCh. 25 - Prob. 56PCh. 25 - Prob. 57PCh. 25 - Prob. 58PCh. 25 - Prob. 59PCh. 25 - Prob. 60PCh. 25 - Prob. 61PCh. 25 - Prob. 62PCh. 25 - Prob. 63PCh. 25 - Prob. 64PCh. 25 - Prob. 65PCh. 25 - Prob. 66PCh. 25 - Prob. 67PCh. 25 - Prob. 68PCh. 25 - Prob. 69PCh. 25 - Prob. 70PCh. 25 - Prob. 71PCh. 25 - Prob. 72PCh. 25 - Prob. 73PCh. 25 - Prob. 74PCh. 25 - Prob. 75PCh. 25 - Prob. 76PCh. 25 - Prob. 77PCh. 25 - Prob. 78PCh. 25 - Prob. 79PCh. 25 - Prob. 80PCh. 25 - Prob. 81PCh. 25 - Prob. 82PCh. 25 - Prob. 83PCh. 25 - Prob. 84PCh. 25 - Prob. 85PCh. 25 - Prob. 86PCh. 25 - Prob. 87PCh. 25 - Prob. 88PCh. 25 - Prob. 89PCh. 25 - Prob. 90PCh. 25 - Prob. 91PCh. 25 - Prob. 92PCh. 25 - Prob. 93PCh. 25 - Prob. 94PCh. 25 - Prob. 95PCh. 25 - Prob. 96PCh. 25 - Is there any way to prevent a hereditary disease?...Ch. 25 - Prob. 98PCh. 25 - Prob. 99PCh. 25 - Prob. 100PCh. 25 - Glycine, alanine, and valine are classified as...Ch. 25 - Prob. 102PCh. 25 - Which polypeptide is coded for by the mRNA...Ch. 25 - -100 A new endonuclease is found. It cleaves...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
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