Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781305176461
Author: Kotz
Publisher: Cengage
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Chapter 25, Problem 6PS
Interpretation Introduction

INTERPRETATION:

The mathematical equations that define the rate of decay should be determined.

CONCEPT INTRODUCTION:

Radioactive decay:

A nucleus undergoes disintegration in-order to become stable by emitting radiations such as alpha, beta and gamma particles.

Radioactive series:

The series in which successive disintegration of unstable nuclei is formed until a stable nucleus is formed. dNdt=-λN

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

Chapter 25 Solutions

Chemistry & Chemical Reactivity

Ch. 25.4 - Prob. 3CYUCh. 25.4 - Prob. 1RCCh. 25.4 - Prob. 2RCCh. 25.5 - Prob. 1CYUCh. 25.5 - Prob. 1RCCh. 25.6 - Prob. 1RCCh. 25.9 - Prob. 1CYUCh. 25.9 - Prob. 1QCh. 25.9 - Prob. 2QCh. 25.9 - Prob. 3QCh. 25.9 - Prob. 4QCh. 25.9 - Prob. 5QCh. 25.9 - Prob. 6QCh. 25.A - Prob. 1QCh. 25.A - Prob. 2QCh. 25.A - Prob. 3QCh. 25.A - Prob. 4QCh. 25 - Prob. 1PSCh. 25 - Prob. 4PSCh. 25 - Prob. 5PSCh. 25 - Prob. 6PSCh. 25 - Prob. 7PSCh. 25 - Prob. 8PSCh. 25 - Prob. 9PSCh. 25 - Prob. 11PSCh. 25 - Prob. 12PSCh. 25 - Prob. 13PSCh. 25 - Prob. 14PSCh. 25 - Prob. 15PSCh. 25 - Prob. 16PSCh. 25 - Prob. 17PSCh. 25 - Prob. 18PSCh. 25 - Prob. 19PSCh. 25 - Prob. 20PSCh. 25 - Prob. 21PSCh. 25 - Prob. 22PSCh. 25 - Prob. 23PSCh. 25 - Prob. 24PSCh. 25 - Prob. 25PSCh. 25 - Prob. 26PSCh. 25 - Prob. 27PSCh. 25 - Prob. 28PSCh. 25 - Prob. 29PSCh. 25 - Prob. 30PSCh. 25 - Prob. 31PSCh. 25 - Prob. 32PSCh. 25 - Prob. 33PSCh. 25 - Prob. 34PSCh. 25 - Prob. 35PSCh. 25 - Prob. 36PSCh. 25 - Prob. 37PSCh. 25 - Prob. 38PSCh. 25 - Prob. 39PSCh. 25 - Prob. 40PSCh. 25 - Prob. 41PSCh. 25 - Prob. 42PSCh. 25 - Prob. 43PSCh. 25 - Prob. 44PSCh. 25 - Prob. 45PSCh. 25 - Some of the reactions explored by Ernest...Ch. 25 - Prob. 47GQCh. 25 - Prob. 48GQCh. 25 - Prob. 49GQCh. 25 - Prob. 50GQCh. 25 - Prob. 51GQCh. 25 - Prob. 52GQCh. 25 - Prob. 53GQCh. 25 - Prob. 54GQCh. 25 - Prob. 55ILCh. 25 - Prob. 56ILCh. 25 - Prob. 57ILCh. 25 - Prob. 58ILCh. 25 - Prob. 59ILCh. 25 - Prob. 60ILCh. 25 - Prob. 61SCQCh. 25 - Prob. 62SCQCh. 25 - Prob. 63SCQCh. 25 - Prob. 64SCQCh. 25 - Prob. 66SCQCh. 25 - Prob. 67SCQCh. 25 - Prob. 68SCQCh. 25 - Prob. 69SCQ
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