The given figure is to be completed by writing the homolytic bond dissociation energies in the boxes, and which radical, Br · and Cl · , is more stable is to be explained. Concept introduction: The energy that would be required to increase the distance between two bonded atoms from the bond length to infinity, that is, breaking of one mole of molecules into their individual atoms, is termed as the bond energy. The larger value of bond energy represents strong bond. Bond dissociation energy of H - Cl is 431 kJ/mol , and that of H - Br is 368 kJ/mol . The high energy radicals are less stable and more reactive.

Question

Want to see the full answer?

Answer 1

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 25, Problem 25.3YT

Interpretation Introduction

Interpretation:

The given figure is to be completed by writing the homolytic bond dissociation energies in the boxes, and which radical, Br· and Cl·, is more stable is to be explained.

Concept introduction:

The energy that would be required to increase the distance between two bonded atoms from the bond length to infinity, that is, breaking of one mole of molecules into their individual atoms, is termed as the bond energy. The larger value of bond energy represents strong bond.

Bond dissociation energy of H - Cl is 431 kJ/mol, and that of H - Br is 368 kJ/mol. The high energy radicals are less stable and more reactive.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Ppplllleeeaaasssseeee hellppp wiithhh thisss physical chemistryyyyy I talked like this because AI is very annoying

For this question, if the product is racemic, input both enantiomers in the same Marvin editor. A) Input the number that corresponds to the reagent which when added to (E)-but-2-ene will result in a racemic product. Input 1 for Cl, in the cold and dark Input 2 for Oy followed by H₂O, Zn Input 3 for D₂ with metal catalyst Input 4 for H₂ with metal catalyst B) Draw the skeletal structure of the major organic product made from the reagent in part A Marvin JS Help Edit drawing C) Draw the skeletal structure of the major organic product formed when (2)-but-2-ene is treated with peroxyacetic acid. Marvin 35 Help

Michael Reactions 19.52 Draw the products from the following Michael addition reactions. 1. H&C CH (a) i 2. H₂O* (b) OEt (c) EtO H₂NEt (d) ΕΙΟ + 1. NaOEt 2. H₂O' H H 1. NaOEt 2. H₂O*

Answer 2

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 25, Problem 25.3YT

Interpretation Introduction

Interpretation:

The given figure is to be completed by writing the homolytic bond dissociation energies in the boxes, and which radical, Br· and Cl·, is more stable is to be explained.

Concept introduction:

The energy that would be required to increase the distance between two bonded atoms from the bond length to infinity, that is, breaking of one mole of molecules into their individual atoms, is termed as the bond energy. The larger value of bond energy represents strong bond.

Bond dissociation energy of H - Cl is 431 kJ/mol, and that of H - Br is 368 kJ/mol. The high energy radicals are less stable and more reactive.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 25, Problem 25.3YT

Interpretation Introduction

Interpretation:

The given figure is to be completed by writing the homolytic bond dissociation energies in the boxes, and which radical, Br· and Cl·, is more stable is to be explained.

Concept introduction:

The energy that would be required to increase the distance between two bonded atoms from the bond length to infinity, that is, breaking of one mole of molecules into their individual atoms, is termed as the bond energy. The larger value of bond energy represents strong bond.

Bond dissociation energy of H - Cl is 431 kJ/mol, and that of H - Br is 368 kJ/mol. The high energy radicals are less stable and more reactive.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 25, Problem 25.3YT

Interpretation Introduction