Organic Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (9th Edition) (New in Organic Chemistry)
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Chapter 25, Problem 25.25SP
Interpretation Introduction

Interpretation: The pictorial representation of typical Olestra molecule with the use of any fatty acids that are commonly found in vegetable oils is to be stated.

Concept introduction: The sucrose molecule in Olestra has six, seven, or eight fatty acids (most commonly) esterified to its hydroxyl group. The fatty acids come from hydrolysis of vegetable oils such as corn, soybean, coconut, palm and cottonseed oils.

To determine: The pictorial representation of typical Olestra molecule with the use of any fatty acids that are commonly found in vegetable oils.

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Classify each of the following molecules as aromatic, antiaromatic, or nonaromatic. ZI NH Explanation Check O aromatic O antiaromatic O nonaromatic O aromatic O antiaromatic H O nonaromatic O aromatic O antiaromatic O nonaromatic ×
Part I. Draw the stepwise reaction mechanism of each product (a, b, c, d, e, f) HO HO OH НОН,С HO OH Sucrose HO CH₂OH H N N HO -H H -OH KMnO4, Heat H OH CH₂OH (d) Phenyl Osatriazole OH НОН,С HO HO + Glacial HOAC HO- HO CH₂OH OH HO Fructose (a) Glucose OH (b) H₂N HN‍ (c) CuSO4-5H2O, ethanol H N N N HO ·H H OH H OH N CH₂OH OH (f) Phenyl Osazone H (e) Carboxy phenyl osatriazole Figure 2.1. Reaction Scheme for the Total Synthesis of Fine Chemicals
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