Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 25, Problem 25.24E
Interpretation Introduction
Interpretation:
The events in maintaining fluid balance by the thirst mechanism are to be stated.
Concept introduction:
Fluid balance in the body is dependent on fluid intake and output. Fluid and electrolyte balance are interrelated. The fluid enters the body in the form of food and drinks and the fluid content of the body is maintained by urine secretion.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 25 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 25 - Prob. 25.1ECh. 25 - Prob. 25.2ECh. 25 - Prob. 25.3ECh. 25 - Prob. 25.4ECh. 25 - Prob. 25.5ECh. 25 - What is the principal anion found in the...Ch. 25 - Prob. 25.7ECh. 25 - Prob. 25.8ECh. 25 - Prob. 25.9ECh. 25 - Prob. 25.10E
Ch. 25 - What term is given to the reversible flow of...Ch. 25 - Prob. 25.12ECh. 25 - Prob. 25.13ECh. 25 - Prob. 25.14ECh. 25 - Prob. 25.15ECh. 25 - Prob. 25.16ECh. 25 - Prob. 25.17ECh. 25 - Prob. 25.18ECh. 25 - Prob. 25.19ECh. 25 - Prob. 25.20ECh. 25 - Prob. 25.21ECh. 25 - Prob. 25.22ECh. 25 - Prob. 25.23ECh. 25 - Prob. 25.24ECh. 25 - Prob. 25.25ECh. 25 - Prob. 25.26ECh. 25 - Prob. 25.27ECh. 25 - Prob. 25.28ECh. 25 - Hemoglobin (HHb) is a weak acid that forms the Hb...Ch. 25 - Prob. 25.30ECh. 25 - Prob. 25.31ECh. 25 - Prob. 25.32ECh. 25 - Prob. 25.33ECh. 25 - Prob. 25.34ECh. 25 - Prob. 25.35ECh. 25 - What ionic shift maintains electron charge balance...Ch. 25 - Prob. 25.37ECh. 25 - Prob. 25.38ECh. 25 - Prob. 25.39ECh. 25 - Prob. 25.40ECh. 25 - Prob. 25.41ECh. 25 - Prob. 25.42ECh. 25 - Prob. 25.43ECh. 25 - Prob. 25.44ECh. 25 - Prob. 25.45ECh. 25 - Prob. 25.46ECh. 25 - Prob. 25.47ECh. 25 - Prob. 25.48ECh. 25 - Prob. 25.49ECh. 25 - Prob. 25.50ECh. 25 - Prob. 25.51ECh. 25 - Prob. 25.52ECh. 25 - Prob. 25.53ECh. 25 - Explain how uncontrolled diarrhea can lead to...Ch. 25 - Prob. 25.55ECh. 25 - Prob. 25.56ECh. 25 - Prob. 25.57ECh. 25 - Prob. 25.58ECh. 25 - Prob. 25.59ECh. 25 - The liquid portion of the blood is called: a....Ch. 25 - Prob. 25.61ECh. 25 - Prob. 25.62ECh. 25 - The hormone most responsible for the renal...Ch. 25 - Prob. 25.64ECh. 25 - Prob. 25.65E
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- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 1 2 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva ×arrow_forwardPredict the products of this organic reaction: Explanation Check IN NaBH3CN H+ ? Click and drag to start drawing a structure. D 5 C +arrow_forwardPredict the products of this organic reaction: H3O+ + ? • Draw all the reasonable products in the drawing area below. If there are no products, because no reaction will occur, check the box under the drawing area. • Include both major and minor products, if some of the products will be more common than others. • Be sure to use wedge and dash bonds if you need to distinguish between enantiomers. No reaction. Click and drag to start drawing a structure. dmarrow_forward
- Iarrow_forwardDraw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option commandarrow_forwardAG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, Narrow_forward
- 4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)arrow_forward2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)arrow_forward5. Consider the compounds shown below as ligands in coordination chemistry and identify their denticity; comment on their ability to form chelate complexes. (6 points) N N A B N N N IN N Carrow_forward
- 1. Use standard reduction potentials to rationalize quantitatively why: (6 points) (a) Al liberates H2 from dilute HCl, but Ag does not; (b) Cl2 liberates Br2 from aqueous KBr solution, but does not liberate C12 from aqueous KCl solution; c) a method of growing Ag crystals is to immerse a zinc foil in an aqueous solution of AgNO3.arrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 3 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? N N H3O+ +R + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure. fmarrow_forward
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