Organic Chemistry, Books a la Carte Edition (9th Edition)
Organic Chemistry, Books a la Carte Edition (9th Edition)
9th Edition
ISBN: 9780134160382
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 25, Problem 25.22SP

(a)

Interpretation Introduction

Interpretation:

The structure of an optically active triglyceride that contains one equivalent of myristic acid and two equivalent of oleic acid is to be stated.

Concept introduction:

The class of glycerides in which all the three glycerol OH groups are esterified, are known as triglycerides. Triglycerides are derived from two or three unsaturated fatty acids or derived from two or three saturated fatty acids or mixture of both.

(b)

Interpretation Introduction

Interpretation:

The structure of an optically inactive triglyceride that contains one equivalent of myristic acid and two equivalent of oleic acid is to be stated.

Concept introduction:

The class of glycerides in which all the three glycerol OH groups are esterified, are known as triglycerides. Triglycerides are derived from two or three unsaturated fatty acids or derived from two or three saturated fatty acids or mixture of both.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100
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