Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 25, Problem 25.10QAP
Quinone undergoes a reversible reduction at a voltammetric working electrode. The reaction is
(a) Assume that the diffusion coefficients for quinone and hydroquinone are approximately the same and calculate the approximate half-wave Potential (versus SCE) for the reduction of hydroquinone at an RDE from a solution buffered to a pH of 8.0.
(b) Repeat the calculation in (a) for a solution buffered to a pH of 5.0.
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Principles of Instrumental Analysis
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- Show work with explanation needed. don't give Ai generated solutionarrow_forwardGive detailed Solution with explanation needed with structures. don't give Ai generated solution. avoid handwritten Solutionarrow_forwardThe acid-base indicator HX undergoes the following reaction in a dilute aqueous solution: HX (color 1) H+ + X- (color 2). The following absorbance data were obtained for a 0.00035 M solution of HX in 0.1 M NaOH and 0.1 M HCI. Measurements were made at wavelengths of 450 nm and 620 nm using a 1.0 cm glass cuvette. 450 620 A(460 nm) A(630 nm) 0.1 M NaOH 0.1 M HCI 0.065 0.435 0.895 0.150 In the 0.1M NaOH solution, the indicator will be almost 100% in the X- form, while in 0.1M HCI, the indicator will be nearly 100% protonated (HX). Calculate the acid dissociation constant for the indicator if a pH=5 buffer solution containing a very small amount of indicator exhibits an absorbance of 0.567 at 450 nm and 0.395 at 620 nm (measured in a 1 cm glass cuvette).arrow_forward
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