
a) Preparation of aniline from benzene
Interpretation:
How to prepare aniline starting from benzene is to be shown.
Concept introduction:
The steps involved in preparing aniline from benzene are i) Nitration of benzene ii) reduction of nitrobenzene.
b) Preparation of aniline from benzamide
Interpretation:
How to prepare aniline starting from benzamide is to be shown.
Concept introduction:
In Hofmann degradation reaction amides when treated with Br2/NaOH are converted into
c) Preparation of aniline from toluene
Interpretation:
How to prepare aniline starting from toluene is to be shown.
Concept introduction:
The steps involved in preparing aniline from toluene are i)Oxidation of methyl group ii) Conversion to acid chloride iii) Conversion in to an amide iv) Hofmann degradation of the amide.

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Chapter 24 Solutions
OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card for McMurry's Organic Chemistry, 9th
- Hi, I need your help with the drawing, please. I have attached the question along with my lab instructions. Please use the reaction from the lab only, as we are not allowed to use outside sources. Thank you!arrow_forwardHi, I need your help i dont know which one to draw please. I’ve attached the question along with my lab instructions. Please use the reaction from the lab only, as we are not allowed to use outside sources. Thank you!arrow_forward5. Write the formation reaction of the following complex compounds from the following reactants: 6. AgNO₃ + K₂CrO₂ + NH₄OH → 7. HgNO₃ + excess KI → 8. Al(NO₃)₃ + excess NaOH →arrow_forward
- Indicate whether the product formed in the reaction exhibits tautomerism. If so, draw the structure of the tautomers. CO₂C2H5 + CH3-NH-NH,arrow_forwardDraw the major product of this reaction N-(cyclohex-1-en-1-yl)-1-(pyrrolidino) reacts with CH2=CHCHO, heat, H3O+arrow_forwardDraw the starting material that would be needed to make this product through an intramolecular Dieckmann reactionarrow_forward
- Draw the major product of this reaction. Nitropropane reacts + pent-3-en-2-one reacts with NaOCH2CH3, CH3CHOHarrow_forwardIndicate whether the product formed in the reaction exhibits tautomerism. If so, draw the structure of the tautomers. OC2H5 + CoHs-NH-NH,arrow_forwardExplain how substitutions at the 5-position of barbituric acid increase the compound's lipophilicity.arrow_forward
- Explain how substitutions at the 5-position of phenobarbital increase the compound's lipophilicity.arrow_forwardName an interesting derivative of barbituric acid, describing its structure.arrow_forwardBriefly describe the synthesis mechanism of barbituric acid from the condensation of urea with a β-diketone.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

