Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 24.6, Problem 19P
Interpretation Introduction

Interpretation:

The enzyme catalysed reaction and the names of the required coenzymes should be determined.

Concept introduction:

In an enzyme catalysed reaction that requires coenzymesB12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbanion.

Biotin (vitamin H) is the coenzyme required by enzymes that catalyse the carboxylation of a carbon adjacent to carbonyl group.

CoenzymesB12: The coenzyme required by enzymes catalyses certain rearrangement reactions.

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Assign ALL signals for the proton and carbon NMR spectra on the following pages.
7.5 1.93 2.05 C B A 4 3 5 The Joh. 9 7 8 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 0.86 OH 10 4 3 5 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 CI 4 3 5 1 2 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 2.21 4.00 1.5 2.00 2.07 1.0 ppm 2.76
Assign the functional group bands on the IR spectra.

Chapter 24 Solutions

Organic Chemistry

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