ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
4th Edition
ISBN: 9781119761105
Author: Klein
Publisher: WILEY
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Chapter 24.4, Problem 7CC
Interpretation Introduction

Interpretation:

For the enantiomer of D-fructose, name and structure should be identified.

Concept introduction:

  • D and L configuration of a sugar are Enantiomers.
  • Enantiomers are non-super imposable mirror images of each other.
  • The stereo-descriptor for other carbohydrates of having more than one chiral center will be evaluated by the location of –OH group (right or left) of farthest chiral carbon from the carbonyl group. Such as,
  • If the –OH group is located in right side then, the carbohydrate is a D-sugar.
  • If the –OH group is located in left side then, the carbohydrate is a L-sugar.

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