The structure of D-gluconic acid should be drawn Concept introduction: The Fischer projection : Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry. The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom. The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar. To find : The structure of D-gluconic acid.

Question

Want to see the full answer?

Answer 1

Question

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Please choose the best reagents to complete the following reaction

Problem 6-17 Look at the following energy diagram: Energy Reaction progress (a) Is AG for the reaction positive or negative? Label it on the diagram. (b) How many steps are involved in the reaction? (c) How many transition states are there? Label them on the diagram. Problem 6-19 What is the difference between a transition state and an intermediate? Problem 6-21 Draw an energy diagram for a two-step reaction with Keq > 1. Label the overall AG°, transition states, and intermediate. Is AG° positive or negative? Problem 6-23 Draw an energy diagram for a reaction with Keq = 1. What is the value of AG° in this reaction?

Problem 6-37 Draw the different monochlorinated constitutional isomers you would obtain by the radical chlorination of the following compounds. (b) (c) Problem 6-39 Show the structure of the carbocation that would result when each of the following alkenes reacts with an acid, H+. (a) (b) (c)

Answer 2

Question

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Answer 6

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

Answer 7

Chapter 24, Problem 86IP

(a)

Interpretation Introduction

Interpretation:

The structure of D-gluconic acid should be drawn

Concept introduction:

The Fischer projection: Fischer projection is a two-dimensional representation of a three-dimensional organic molecule by projection. It is mainly proposed for the representation of carbohydrate chemistry.

The orientation of the carbon atoms in a molecule is arranged vertically from top to bottom.

The C1 carbon is at the top of the orientation, the hydrogen and hydroxyl groups are placed in right and left side of the orientation. D and L form are depends on the arrangement of the hydroxyl group. If the hydroxyl group is in the right side of the molecule in the penultimate (next-to-last) carbon is called as D sugar, if the If the hydroxyl group is in the left side of the molecule in the penultimate (next-to-last) carbon is called as L sugar.

To find: The structure of D-gluconic acid.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of lactone should be drawn and the configuration at eachchirality center identified.

Concept introduction:

The Haworth projection: A Haworth projection is a three-dimensional representation of monosaccharides and the structural formula is inscription as a cyclic structures.

In Haworth projection, oxygen atom is placed in back right corner, CH2OH is arranged up at the C5 carbon atom. Anomeric hydroxyl group is placed down if it is α-anomer which is trans to the CH2OH of C5 carbon. The remaining hydroxyl group is placed up if the hydroxyl group left side in Fischer projection. Hydroxyl group is placed down if the hydroxyl group right side in Fischer projection

To find: The structure of lactone.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Difference between the D-gluconic acid and the lactone using IR Spectroscopy should be explained

Concept introduction:

Infra-red (IR) spectroscopy: Infra-red (IR) spectroscopy deals with the interaction between a molecule and radiation from the IR region of the electromagnetic spectrum (IR region = 4000 - 400 cm^-1). IR radiation causes the excitation of the vibrations of covalent bonds within that molecule, which include the stretching and bending.

To find: Difference between the D-gluconic acid and the lactone using IR Spectroscopy.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 24.2 - Prob. 1CC Ch. 24.2 - Prob. 2CC Ch. 24.2 - Prob. 3CC Ch. 24.2 - Prob. 4CC Ch. 24.2 - Prob. 5CC Ch. 24.2 - Prob. 6CC Ch. 24.4 - Prob. 7CC Ch. 24.4 - Prob. 8CC Ch. 24.5 - Prob. 1LTS Ch. 24.5 - Prob. 9PTS

Interpretation: The Optical activity of lactone should be identified. Concept introduction: Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active. To find: Optically activity of lactone.

Want to see the full answer?

Chapter 24 Solutions

Interpretation:

The Optical activity of lactone should be identified.

Concept introduction:

Optical activity: molecule or substances that can rotate the plane-polarized light are said to be optically active.

To find: Optically activity of lactone.