CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
4th Edition
ISBN: 9781260562620
Author: SMITH
Publisher: MCG
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Chapter 24.3, Problem 24.2P
Interpretation Introduction
Interpretation:
The energy required for the phosphorylation of fructose-6-phosphate needs to be determined.
Concept introduction:
For a coupled reaction, the amount of energy involved in the reaction is sum of amount of energies involved in the reactions with the help of which the coupled reaction is obtained. When the energy is released in the reaction, the energy change is reported as negative value. When the energy is absorbed in the reaction, the energy is reported as a positive value
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 24 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
Ch. 24.2 - Analyze the following reaction by considering the...Ch. 24.2 - Prob. 24.2PPCh. 24.3 - Prob. 24.1PCh. 24.3 - Prob. 24.2PCh. 24.3 - Prob. 24.3PCh. 24.3 - Prob. 24.4PCh. 24.3 - Prob. 24.5PCh. 24.3 - Prob. 24.6PCh. 24.4 - Prob. 24.7PCh. 24.4 - Prob. 24.8P
Ch. 24.4 - Prob. 24.9PCh. 24.5 - Prob. 24.10PCh. 24.5 - Prob. 24.11PCh. 24.5 - Prob. 24.12PCh. 24.6 - Prob. 24.13PCh. 24.7 - Prob. 24.14PCh. 24.7 - Prob. 24.3PPCh. 24.7 - Prob. 24.15PCh. 24.7 - Prob. 24.16PCh. 24.7 - Use the number of molecules of ATP formed from the...Ch. 24.7 - Prob. 24.18PCh. 24.8 - Prob. 24.19PCh. 24.8 - Prob. 24.20PCh. 24.8 - Prob. 24.21PCh. 24.9 - Prob. 24.4PPCh. 24.9 - What products are formed when each amino acid is...Ch. 24.9 - Prob. 24.22PCh. 24 - Analyze each reaction by considering the...Ch. 24 - Analyze each reaction by considering the...Ch. 24 - Prob. 25PCh. 24 - Prob. 26PCh. 24 - Prob. 27PCh. 24 - Prob. 28PCh. 24 - Prob. 29PCh. 24 - Prob. 30PCh. 24 - Prob. 31PCh. 24 - Prob. 32PCh. 24 - Glucose is completely metabolized to six molecules...Ch. 24 - Why is glycolysis described as an anaerobic...Ch. 24 - Write the overall equation with key coenzymes for...Ch. 24 - Prob. 36PCh. 24 - Prob. 37PCh. 24 - Prob. 38PCh. 24 - Consider the aerobic and anaerobic avenues of...Ch. 24 - Prob. 40PCh. 24 - Prob. 41PCh. 24 - Prob. 42PCh. 24 - Prob. 43PCh. 24 - Prob. 44PCh. 24 - Prob. 45PCh. 24 - Prob. 46PCh. 24 - Prob. 47PCh. 24 - Prob. 48PCh. 24 - Prob. 49PCh. 24 - Prob. 50PCh. 24 - Prob. 51PCh. 24 - Prob. 52PCh. 24 - Prob. 53PCh. 24 - Prob. 54PCh. 24 - Prob. 55PCh. 24 - Prob. 56PCh. 24 - Prob. 57PCh. 24 - Prob. 58PCh. 24 - Prob. 59PCh. 24 - How much ATP is generated by the complete...Ch. 24 - Prob. 61PCh. 24 - Fill in the boxes with the number of moles of each...Ch. 24 - Prob. 63PCh. 24 - Prob. 64PCh. 24 - Prob. 65PCh. 24 - Prob. 66PCh. 24 - Prob. 67PCh. 24 - Prob. 68PCh. 24 - Prob. 69PCh. 24 - Prob. 70PCh. 24 - What is the difference between ketogenic and...Ch. 24 - Prob. 72PCh. 24 - Prob. 73PCh. 24 - Draw the structure of the keto acid formed by the...Ch. 24 - Draw the products formed in each transamination...Ch. 24 - Prob. 76PCh. 24 - Prob. 77PCh. 24 - Prob. 78PCh. 24 - Prob. 79PCh. 24 - Prob. 80PCh. 24 - What metabolic intermediate is formed from the...Ch. 24 - What metabolic intermediate is formed from the...Ch. 24 - Prob. 83PCh. 24 - Prob. 84PCh. 24 - Prob. 85PCh. 24 - Prob. 86PCh. 24 - Prob. 87PCh. 24 - What is the cause of the pain and cramping in a...Ch. 24 - Prob. 89PCh. 24 - Prob. 90PCh. 24 - Prob. 91PCh. 24 - Prob. 92PCh. 24 - Prob. 93PCh. 24 - Prob. 94PCh. 24 - What type of enzyme would catalyze the conversion...Ch. 24 - Prob. 96PCh. 24 - Prob. 97CPCh. 24 - Prob. 98CPCh. 24 - Prob. 99CPCh. 24 - Prob. 100CP
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