ORGANIC CHEMISTRY-PRINT MULTI TERM
ORGANIC CHEMISTRY-PRINT MULTI TERM
4th Edition
ISBN: 9781119832614
Author: Klein
Publisher: WILEY
Question
Book Icon
Chapter 24.2, Problem 6CC

(a)

Interpretation Introduction

Interpretation:

For the four stereo isomeric aldotetroses, the pair of enantiomers and stereo descriptors is needed to be drawn.

Concept introduction:

  • Aldoses are monosaccharides, which contains Aldehyde group.
  • The naming of monosaccharides,
    • Prefix: aldo or keto indicates whether the monosaccharide is containing aldehyde or ketone group.
    • Suffix: ose indicates the carbohydrates
    • Root word: indicate the number of carbons.
  • The stereo-descriptor used for monosaccharides is D or L. it is based on the dextrorotatory glyceraldehyde or levorotatory glyceraldehyde.

    ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 6CC , additional homework tip  1

    The stereo-descriptor for other carbohydrates of having more than one chiral center will be evaluated by the location of –OH group (right or left) of farthest chiral carbon from the carbonyl group. Such as,

    If the –OH group is located in right side then, the carbohydrate is a D-sugar.

    If the –OH group is located in left side then, the carbohydrate is a L-sugar.

  • Enantiomers are non-super imposable mirror images of each other.

To determine: the structures of pair of enantiomers of stereo isomeric aldotetroses.

ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 6CC , additional homework tip  2ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 6CC , additional homework tip  3

(b)

Interpretation Introduction

Interpretation:

For the four stereo isomeric aldotetroses, the pair of enantiomers and stereo descriptors is needed to be drawn.

Concept introduction:

  • Aldoses are monosaccharides, which contains Aldehyde group.
  • The naming of monosaccharides,
    • Prefix: aldo or keto indicates whether the monosaccharide is containing aldehyde or ketone group.
    • Suffix: ose indicates the carbohydrates
    • Root word: indicate the number of carbons.
  • The stereo-descriptor used for monosaccharides is D or L. it is based on the dextrorotatory glyceraldehyde or levorotatory glyceraldehyde.

    ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 6CC , additional homework tip  4

    The stereo-descriptor for other carbohydrates of having more than one chiral center will be evaluated by the location of –OH group (right or left) of farthest chiral carbon from the carbonyl group. Such as,

    If the –OH group is located in right side then, the carbohydrate is a D-sugar.

    If the –OH group is located in left side then, the carbohydrate is a L-sugar.

  • Enantiomers are non-super imposable mirror images of each other.

To identify: the D sugar and L sugar from the four structures of stereo isomeric aldotetroses.

ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 6CC , additional homework tip  5

Blurred answer
Students have asked these similar questions
||| 7:47 ull 57% ← Problem 19 of 48 Submit Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the product of this carbocation rearrangement. Include all lone pairs and charges as appropriate. H 1,2-alkyl shift +
Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.
Below is the SN1 reaction of (S)-3-chlorocyclohexene and hydroxide (OH). Draw the missing curved arrows, lone pairs of electrons, and nonzero formal charges. In the third box, draw the two enantiomeric products that will be produced. 5th attempt Please draw all four bonds at chiral centers. Draw the two enantiomeric products that will be produced. Draw in any hydrogen at chiral centers. 1000 4th attempt Feedback Please draw all four bonds at chiral centers. 8. R5 HO: See Periodic Table See Hint H Cl Br Jid See Periodic Table See Hint

Chapter 24 Solutions

ORGANIC CHEMISTRY-PRINT MULTI TERM

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY