ORGANIC CHEMISTRY-PRINT MULTI TERM
ORGANIC CHEMISTRY-PRINT MULTI TERM
4th Edition
ISBN: 9781119832614
Author: Klein
Publisher: WILEY
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Chapter 24.2, Problem 4CC

(a)

Interpretation Introduction

Interpretation:

The Fischer projection of D-Allose and L-Allose are needed to be determined if the four chirality centers of D-Allose are in R-configuration.

Concept introduction:

  • Fischer projection of carbohydrates are drawn by vertical line representing the cyclic carbon chain and the attached OH and H groups are placed in right or left side of each carbon atoms. The position of carbonyl group is on top of the line.
  • R and S configuration of chiral carbons of carbohydrates are depending upon the location of –OH groups on the each carbon atom in Fischer projection.
  • If the –OH group is in right side then, the configuration is R.
  • If the –OH group is in left side then, the configuration is S.
  • D and L configuration of a sugar are Enantiomers.
  • Enantiomers are non-super imposable mirror images of each other.

To draw: the Fischer projection of D-Allose, if the four chirality centers of D-Allose are in R-configuration.

ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 4CC , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

The Fischer projection of D-Allose and L-Allose are needed to be determined if the four chirality centers of D-Allose are in R-configuration.

Concept introduction:

  • Fischer projection of carbohydrates are drawn by vertical line representing the cyclic carbon chain and the attached OH and H groups are placed in right or left side of each carbon atoms. The position of carbonyl group is on top of the line.
  • R and S configuration of chiral carbons of carbohydrates are depending upon the location of –OH groups on the each carbon atom in Fischer projection.
  • If the –OH group is in right side then, the configuration is R.
  • If the –OH group is in left side then, the configuration is S.
  • D and L configuration of a sugar are Enantiomers.
  • Enantiomers are non-super imposable mirror images of each other.

 To draw: the Fischer projection of L-Allose.

ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 24.2, Problem 4CC , additional homework tip  2

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Chapter 24 Solutions

ORGANIC CHEMISTRY-PRINT MULTI TERM

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