ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 24.14, Problem 17P
Interpretation Introduction

Interpretation:

The curved arrows are to be added to the given sequence to show the conversion of the conjugate acid of methyl-β-D-glucopyranoside to the corresponding α-anomer.

Concept introduction:

The flow of electrons in the mechanism is shown by curved arrows.

The compound methyl-β-D-glucofuranoside can be converted to its anomer using unshared electron pair on the oxygen attached to C-5 carbon atom.

The product of each step gives ideas about the bonds that break and new bonds that are formed.

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