(a) Interpretation: The structure of the chelate complex [Pt (ox) 2 ]2- needs to be drawn. Concept introduction: Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

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Answer 1

Question

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

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Answer 3

Question

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

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Answer 4

Question

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

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Answer 5

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 6

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 7

Chapter 24, Problem 8E

Interpretation Introduction

(a)

Interpretation:

The structure of the chelate complex [Pt (ox) ₂]2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the chelate complex [Cr (ox) ₃]3- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the chelate complex [Fe (EDTA)] 2- needs to be drawn.

Concept introduction:

Chelation is the process of bonding metal ion to other molecules and ions. The central atom is linked with two or more polydentate ligands by coordination bonds. These are called as chelates. There are many agents and oxalates is one of them. The oxalate ion is a bidentate ligand having four oxygen atoms with lone pairs.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 24 - Prob. 1E Ch. 24 - Prob. 2E Ch. 24 - Prob. 3E Ch. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5E Ch. 24 - Prob. 6E Ch. 24 - Prob. 7E Ch. 24 - Prob. 8E Ch. 24 - Prob. 9E Ch. 24 - Prob. 10E

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Chapter 24 Solutions