Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 24, Problem 54P
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Interpretation: The disease studied for treatment with siRNA drugs explained.
Concept introduction: siRNA’s short segments bind to mRNA.
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Which of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.
Draw the stepwise mechanism (with arrow pushing)
a) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product.
b) Draw the reaction coordinate diagram for the reaction pathway generating each product.
c) State the Arrhenius Equation and explain the terms with their physical significance.
d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?
Chapter 24 Solutions
Introduction to General, Organic and Biochemistry
Ch. 24.2 - Problem 25-1 Draw the structure of UMP.Ch. 24.3 - Prob. 24.2QCCh. 24.3 - Prob. 24.3QCCh. 24.4 - Prob. 24.4QCCh. 24.5 - Prob. 24.5QCCh. 24.6 - Prob. 24.6QCCh. 24.7 - Prob. 24.7QCCh. 24.8 - Prob. 24.8QCCh. 24 - Prob. 1PCh. 24 - 25-2 What structures Of the cell, visible in a...
Ch. 24 - 25-3 Name one hereditary disease.Ch. 24 - 25-4 What is the basis unit of heredity?Ch. 24 - 25-5 (a) Where in a cell is the DNA located? (b)...Ch. 24 - 25-6 What are the components of (a) a nucleotide...Ch. 24 - 25-7 What are the differences between DNA and RNA?Ch. 24 - 25-8 Draw the structures of ADP and GDP. Are these...Ch. 24 - Prob. 9PCh. 24 - 25-10 Which DNA and RNA bases contain a carbonyl...Ch. 24 - Prob. 11PCh. 24 - Prob. 12PCh. 24 - Prob. 13PCh. 24 - Prob. 14PCh. 24 - Prob. 15PCh. 24 - Prob. 16PCh. 24 - Prob. 17PCh. 24 - 25-18 What type of bond connects the base to the...Ch. 24 - Prob. 19PCh. 24 - 25-20 What constitutes the backbone of DNA?Ch. 24 - Prob. 21PCh. 24 - 25-22 In DNA, which carbon atoms of...Ch. 24 - 25-23 The sequence Of a short DNA segment is...Ch. 24 - Prob. 24PCh. 24 - Prob. 25PCh. 24 - Prob. 26PCh. 24 - Prob. 27PCh. 24 - Prob. 28PCh. 24 - 25-29 What constitutes the superstructure of...Ch. 24 - 25-30 What is the primary structure of DNA?Ch. 24 - 25-31 What is the secondary structure of DNA?Ch. 24 - 25-32 What is the major groove of a DNA helix?Ch. 24 - 25-33 What are the higher-order structures of DNA...Ch. 24 - 25-34 Which type Of RNA has enzyme activity? Where...Ch. 24 - 25-35 Which has the longest chains: tRNA, mRNA, or...Ch. 24 - 25-36 Which type of RNA contains modified...Ch. 24 - 25-37 Which type Of RNA has a sequence exactly...Ch. 24 - 25-38 Where is rRNA located in the cell?Ch. 24 - Prob. 39PCh. 24 - Prob. 40PCh. 24 - Prob. 41PCh. 24 - Prob. 42PCh. 24 - Prob. 43PCh. 24 - 25-50 Define: (a) Intron (b) ExonCh. 24 - 25-51 Does mRNA also have introns and exons?...Ch. 24 - Prob. 46PCh. 24 - Prob. 47PCh. 24 - 25-54 Do all genes code for a protein? If not,...Ch. 24 - Prob. 49PCh. 24 - Prob. 50PCh. 24 - Prob. 51PCh. 24 - Prob. 52PCh. 24 - Prob. 53PCh. 24 - Prob. 54PCh. 24 - Prob. 55PCh. 24 - Prob. 56PCh. 24 - 25-55 A DNA molecule normally replicates itself...Ch. 24 - 25-56 Which functional groups on the bases form...Ch. 24 - Prob. 59PCh. 24 - 25-58 Draw the structures of cytosine and guanine...Ch. 24 - 25-59 How many different bases are present in a...Ch. 24 - Prob. 62PCh. 24 - 25-61 Why is replication called semiconservative?Ch. 24 - 25-62 How does the removal of some positive...Ch. 24 - 25-63 Write the chemical reaction for the...Ch. 24 - Prob. 66PCh. 24 - 25-65 What are helicases? What is their function?Ch. 24 - 25-66 Can dATP Serve as a source for a primer?Ch. 24 - Prob. 69PCh. 24 - Prob. 70PCh. 24 - 25-69 In which direction is the DNA molecule...Ch. 24 - Prob. 72PCh. 24 - Prob. 73PCh. 24 - Prob. 74PCh. 24 - 25-73 From the perspective of the chain being...Ch. 24 - Prob. 76PCh. 24 - Prob. 77PCh. 24 - Prob. 78PCh. 24 - Prob. 79PCh. 24 - Prob. 80PCh. 24 - Prob. 81PCh. 24 - Prob. 82PCh. 24 - Prob. 83PCh. 24 - Prob. 84PCh. 24 - Prob. 85PCh. 24 - Prob. 86PCh. 24 - Prob. 87PCh. 24 - Prob. 88PCh. 24 - Prob. 89PCh. 24 - Prob. 90PCh. 24 - Prob. 91PCh. 24 - Prob. 92PCh. 24 - Prob. 93PCh. 24 - (Chemical Connections 24E) What gene associated...Ch. 24 - Prob. 95PCh. 24 - -104 Why is it important that a DNA molecule be...Ch. 24 - Prob. 97PCh. 24 - Prob. 98PCh. 24 - Prob. 99PCh. 24 - Prob. 100PCh. 24 - -109 In sheep DNA, the mol% of adenine (A) was...Ch. 24 - Prob. 102PCh. 24 - Prob. 103PCh. 24 - Prob. 104PCh. 24 - Prob. 105PCh. 24 - -114 How could life have evolved if DNA leads to...Ch. 24 - Prob. 107PCh. 24 - Prob. 108PCh. 24 - Prob. 109P
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- Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium boratearrow_forwardUsing the table of Reactants and Products provided provide the correct letter that corresponds with the Carboxylic acid that is formed in the reaction below. 6 M NaOH Acid-workup WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES A) Pool of Reagents for Part B CI B) OH C) E) CI J) racemic F) K) OH N) OH P) G) OH D) HO H) L) M) HO Q) R) CI Aarrow_forwardIn the table below, the exact chemical structures for Methyl salicylate can be represented by the letter WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES CI B) A) E) Cl racemic F) J) CI K) N) OH P) Pool of Reagents for Part B OH OH G) L) OH D) HO H) M) HO Q) R) CIarrow_forward
- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
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