Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 24, Problem 44QP
Interpretation Introduction
Interpretation:
The balanced equation for the preparation of nitrogen is to be determined.
Concept introduction:
A
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Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 24 Solutions
Chemistry
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Ch. 24 - Elements number 17 and 20 form compounds with...Ch. 24 - Give an example of hydrogen as (a) an oxidizing...Ch. 24 - Prob. 13QPCh. 24 - Prob. 14QPCh. 24 - Prob. 15QPCh. 24 - Prob. 16QPCh. 24 - Prob. 17QPCh. 24 - Prob. 18QPCh. 24 - Prob. 19QPCh. 24 - Prob. 20QPCh. 24 - Briefly discuss the preparation and properties of...Ch. 24 - Prob. 22QPCh. 24 - Prob. 23QPCh. 24 - Prob. 24QPCh. 24 - Prob. 25QPCh. 24 - Prob. 26QPCh. 24 - Prob. 27QPCh. 24 - Prob. 28QPCh. 24 - Prob. 29QPCh. 24 - Prob. 30QPCh. 24 - 24.31 Sodium hydroxide is hygroscopic-that is. it...Ch. 24 - Prob. 32QPCh. 24 - Prob. 33QPCh. 24 - 24.34 Describe a laboratory and an industrial...Ch. 24 - Prob. 35QPCh. 24 - Prob. 36QPCh. 24 - Prob. 37QPCh. 24 - Prob. 38QPCh. 24 - Prob. 39QPCh. 24 - Prob. 40QPCh. 24 - Prob. 41QPCh. 24 - Prob. 42QPCh. 24 - Prob. 43QPCh. 24 - Prob. 44QPCh. 24 - Prob. 45QPCh. 24 - Prob. 46QPCh. 24 - Prob. 47QPCh. 24 - Prob. 48QPCh. 24 - Prob. 49QPCh. 24 - Prob. 50QPCh. 24 - Prob. 51QPCh. 24 - Prob. 52QPCh. 24 - Prob. 53QPCh. 24 - Prob. 54QPCh. 24 - Prob. 55QPCh. 24 - Prob. 56QPCh. 24 - Describe one industrial and one laboratory...Ch. 24 - Prob. 58QPCh. 24 - Prob. 59QPCh. 24 - Prob. 60QPCh. 24 - Prob. 61QPCh. 24 - Prob. 62QPCh. 24 - Prob. 63QPCh. 24 - Prob. 64QPCh. 24 - Prob. 65QPCh. 24 - Prob. 66QPCh. 24 - Prob. 67QPCh. 24 - Prob. 68QPCh. 24 - Prob. 69QPCh. 24 - Prob. 70QPCh. 24 - Prob. 71QPCh. 24 - Prob. 72QPCh. 24 - Prob. 73QPCh. 24 - Prob. 74QPCh. 24 - Prob. 75QPCh. 24 - 24.76 Describe two reactions in which sulfuric...Ch. 24 - Prob. 77QPCh. 24 - Prob. 78QPCh. 24 - Prob. 79QPCh. 24 - Prob. 80QPCh. 24 - Prob. 81QPCh. 24 - Prob. 82QPCh. 24 - Prob. 83QPCh. 24 - Prob. 84QPCh. 24 - Prob. 85QPCh. 24 - Prob. 86QPCh. 24 - Prob. 87QPCh. 24 - Prob. 88QPCh. 24 - Prob. 89APCh. 24 - Prob. 90APCh. 24 - Prob. 91APCh. 24 - Prob. 92APCh. 24 - Prob. 93APCh. 24 - Prob. 94APCh. 24 - Prob. 95APCh. 24 - 24.96 Consider the Frasch process, (a) How is it...Ch. 24 - Prob. 97APCh. 24 - Prob. 98APCh. 24 - Prob. 99APCh. 24 - Life evolves to adapt to its environment. In this...Ch. 24 - Prob. 101APCh. 24 - Prob. 102APCh. 24 - Prob. 103APCh. 24 - Prob. 104APCh. 24 - Prob. 1SEPPCh. 24 - Prob. 2SEPPCh. 24 - Prob. 3SEPPCh. 24 - Prob. 4SEPP
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