ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 24, Problem 24.8P
Interpretation Introduction

(a)

Interpretation:

The name of the aldose is to be stated. The Fischer projection of the aldose is to be drawn.

Concept introduction:

Aldose is a carbohydrate which contains an aldehyde group. Furanose is the cyclic form of the aldose which consists of a five-membered ring made up of four carbon atoms and one oxygen atom. The furanose ring is substituted with hydroxy groups, hydrogen atoms, and a CH2OH group. Fischer projections is a two dimensional representation of organic compounds. It was proposed to represent glucose molecules.

Interpretation Introduction

(b)

Interpretation:

The name of the aldose is to be stated. The carbons which have same and different configuration from glucose are to be identified.

Concept introduction:

Aldose is a carbohydrate which contains an aldehyde group. Pyranose is the cyclic form of the aldose which consists of a six-membered ring made up of four carbon atoms and one oxygen atom. The pyranose ring is substituted with hydroxy groups, hydrogen atoms, and a CH2OH group.

Interpretation Introduction

(c)

Interpretation:

The name of the aldose is to be stated. The Fischer projection of the aldose is to be drawn.

Concept introduction:

Aldose is a carbohydrate which contains an aldehyde group. Furanose is the cyclic form of the aldose which consists of a five-membered ring made up of four carbon atoms and one oxygen atom. The furanose ring is substituted with hydroxy groups, hydrogen atoms, and a CH2OH group. The carbon atom adjacent to the oxygen atom which is substituted by the hydroxyl group is known as anomeric carbon.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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