PRINCIPLES OF INSTRUMENTAL ANALYSIS
7th Edition
ISBN: 9789353506193
Author: Skoog
Publisher: CENGAGE L
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Textbook Question
Chapter 24, Problem 24.4QAP
Halide ions can he deposited at a silver anode, the reaction being
Ag(s) + X-
Suppose that a cell was formed by immersing a silver anode in an analyte solution that was 0.0250 M Cl-,Br-, and I -ions and connecting the half-cell to a saturated calomel cathode via a salt bridge.
(a) Which halide would form first and at what potential? Is the cell galvanic or electrolytic?
(b) Could I- and Br- be separated quantitatively? (Take 1.00 × l0-5 M as the criterion for quantitative removal of an ion.) If a separation is feasible, what range of cell potential could he used?
(c) Repeat part (b) for I- and Cl-.
(d) Repeat part (b) for Br- and Cl-.
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Check the box under each structure in the table that is an enantiomer of the molecule shown below. If none of them are, check the none of the above box under
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Molecule 1
Molecule 2
Molecule 3
----|||
Molecule 4
Molecule 5
Molecule 6
none of the above
mm..
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Chapter 24 Solutions
PRINCIPLES OF INSTRUMENTAL ANALYSIS
Ch. 24 - Prob. 24.1QAPCh. 24 - Calculate the minimum difference in standard...Ch. 24 - Prob. 24.3QAPCh. 24 - Halide ions can he deposited at a silver anode,...Ch. 24 - What cathode potential (versus SCE) would be...Ch. 24 - Calculate the Lime required for a constant current...Ch. 24 - Calculate the time required for a constant current...Ch. 24 - Prob. 24.8QAPCh. 24 - Prob. 24.9QAPCh. 24 - A 0.0712-g sample of a purified organic acid was...
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