Which molecule, C or D, will react faster with ethane in a Diels-Alder reaction is to be explained. Concept introduction: The [4+2] cycloaddition reactions are generally known as a Diels-Alder reaction. A Diels-Alder reaction involves a diene and a dienophile. A diene shares four π electrons from the two conjugated π bonds while a dienophile shares two p electrons from a single π bond. The Diels-Alder reaction is concerted and proceeds through a six-membered aromatic transition state. For a Diels-Alder reaction to occur, the diene must be present in the s-cis conformation because both ends of the diene must be relatively close to the dienophile in the transition state. s indicates that the cis designation describes the orientation of groups about a single bond, rather than a double bond or the plane of the ring. The s-trans conformation of the diene is more stable than s- cis conformation due to steric repulsion. Thus, the conformer which easily undergoes s-cis form will react readily with a dienophile.
Which molecule, C or D, will react faster with ethane in a Diels-Alder reaction is to be explained. Concept introduction: The [4+2] cycloaddition reactions are generally known as a Diels-Alder reaction. A Diels-Alder reaction involves a diene and a dienophile. A diene shares four π electrons from the two conjugated π bonds while a dienophile shares two p electrons from a single π bond. The Diels-Alder reaction is concerted and proceeds through a six-membered aromatic transition state. For a Diels-Alder reaction to occur, the diene must be present in the s-cis conformation because both ends of the diene must be relatively close to the dienophile in the transition state. s indicates that the cis designation describes the orientation of groups about a single bond, rather than a double bond or the plane of the ring. The s-trans conformation of the diene is more stable than s- cis conformation due to steric repulsion. Thus, the conformer which easily undergoes s-cis form will react readily with a dienophile.
Definition Definition Organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Aromatic organic compounds, also called arenes, are an important class of hydrocarbons under the branch of organic chemistry.
Chapter 24, Problem 24.4P
Interpretation Introduction
Interpretation:
Which molecule, C or D, will react faster with ethane in a Diels-Alder reaction is to be explained.
Concept introduction:
The [4+2] cycloaddition reactions are generally known as a Diels-Alder reaction. A Diels-Alder reaction involves a diene and a dienophile. A diene shares four π electrons from the two conjugated π bonds while a dienophile shares two p electrons from a single π bond. The Diels-Alder reaction is concerted and proceeds through a six-membered aromatic transition state. For a Diels-Alder reaction to occur, the diene must be present in the s-cis conformation because both ends of the diene must be relatively close to the dienophile in the transition state. s indicates that the cis designation describes the orientation of groups about a single bond, rather than a double bond or the plane of the ring. The s-trans conformation of the diene is more stable than s- cis conformation due to steric repulsion. Thus, the conformer which easily undergoes s-cis form will react readily with a dienophile.
