
a)
Interpretation:
The limit of the square-root term as
To calculate the limit of the square-root term as
a)

Answer to Problem 24.35P
The limit of the square-root term as
The limit of the square-root term as
Explanation of Solution
As
As
b)
Interpretation:
The
To calculate the
b)

Answer to Problem 24.35P
Explanation of Solution
As
As
c)
Interpretation:
The maximum number of theoretical plates in 50 m long column with 0.10 mm radius fir k=5.0 has to be calculated.
To calculate the maximum number of theoretical plates in 50 m long column with 0.10 mm radius fir k=5.0
c)

Answer to Problem 24.35P
The maximum number of theoretical plates in 50 m long column with 0.10 mm radius fir k=5.0 is found to be
Explanation of Solution
For
The number of plates is calculated as,
Number of plates =
Number of plates =
d)
Interpretation:
The relationship between phase ratio and thickness of stationary column in wall coated column and inside the radius of column has to be derived.
To derive the relationship between phase ratio and thickness of stationary column in wall coated column and inside the radius of column
d)

Explanation of Solution
Phase ratio
The volume of mobile phase divided by the volume of the stationary phase is called as dimensionless phase ratio. The phase ratio is calculated as,
Where,
Increase in thickness of stationary phase, decreases in
e)
Interpretation:
The value of k has to be calculated if
To calculate the value of k
e)

Answer to Problem 24.35P
The value of k is found to be
Explanation of Solution
where ,
For length of column l,
Volume of mobile phase =
Volume of stationary phase =
Substitute these values in equation of k,
The value of k =
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Chapter 24 Solutions
Quantitative Chemical Analysis
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