Name the following compounds: (a) CH 3 ─C≡C─CH 2 ─CH 3

Question

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Answer 1

Textbook Question

Chapter 24, Problem 24.26QP

Name the following compounds:

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 1

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 2

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 3

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 4

(a) CH₃─C≡C─CH₂─CH₃

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 5

a)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

b)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

c)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

d)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

e)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

f)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.

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Answer 2

Textbook Question

Chapter 24, Problem 24.26QP

Name the following compounds:

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 1

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 2

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 3

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 4

(a) CH₃─C≡C─CH₂─CH₃

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 5

a)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

b)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

c)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

d)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

e)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

f)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.

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Answer 3

Textbook Question

Chapter 24, Problem 24.26QP

Name the following compounds:

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 1

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 2

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 3

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 4

(a) CH₃─C≡C─CH₂─CH₃

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 5

a)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

b)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

c)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

d)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

e)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

f)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.

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Answer 4

Textbook Question

Chapter 24, Problem 24.26QP

Name the following compounds:

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 1

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 2

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 3

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 4

(a) CH₃─C≡C─CH₂─CH₃

Chapter 24, Problem 24.26QP, Name the following compounds: (a) CH3CCCH2CH3 , example 5

a)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

b)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

c)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

d)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

e)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

f)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.

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Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

a)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

b)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

c)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

d)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

e)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

f)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.

Answer 8

a)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

Answer 9

a)

Expert Solution

Answer 10

a)

Expert Solution

Answer 11

Expert Solution

Answer 12

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 13

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 1

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 2

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 3

At each Carbon of 2 one methyl group is present. Hence, the structure containing one substituents, then prefix ‘2-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2-methylpentane.

Answer 14

b)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

Answer 15

b)

Expert Solution

Answer 16

b)

Expert Solution

Answer 17

Expert Solution

Answer 18

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 19

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 4

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 5

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENTANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 6

At each Carbon of 2, 3, and 4 one methyl group is present. Hence, the structure containing three identical substituents, then prefix ‘2,3,4-trimethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 2,3,4-trimethylpentane.

Answer 20

c)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

Answer 21

c)

Expert Solution

Answer 22

c)

Expert Solution

Answer 23

Expert Solution

Answer 24

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 25

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 7

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 8

The longest continuous carbon chain of carbon atoms contains six carbons and the parent name is HEXANE. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 9

At each Carbon of 3 one ethyl group is present. Hence, the structure containing one substituent, then prefix ‘3-ethyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-ethylhexane.

Answer 26

d)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

Answer 27

d)

Expert Solution

Answer 28

d)

Expert Solution

Answer 29

Expert Solution

Answer 30

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 31

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 10

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 11

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is 1,4-PENTDIENE. The Suffix ‘diene’ represents the structure contains two double bonds at C-1 and C-4.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 12

At each Carbon of 3 one methyl group is present. Hence, the structure containing one substituent, then prefix ‘3-methyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-methyl-1,4-pentadiene.

Answer 32

e)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

Answer 33

e)

Expert Solution

Answer 34

e)

Expert Solution

Answer 35

Expert Solution

Answer 36

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the substituent should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘yne’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 37

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 13

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 14

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-2-YNE. The Suffix ‘2-yne’ represents the structure contains one triple bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 15

No substituents present and no prefix can be written. Hence, the name is,

IUPAC name: Pent-2-yne.

Answer 38

f)

Expert Solution

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.

Answer 39

f)

Expert Solution

Answer 40

f)

Expert Solution

Answer 41

Expert Solution

Answer 42

Interpretation Introduction

Interpretation:

The given structure has to be named.

Concept introduction:

IUPAC Nomenclature for alkene:

The longest continuous chain of carbon atoms is identified.
The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
While numbering the longest chain, the double bond should get least possible number.
Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 16

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

Answer 43

Explanation of Solution

Given structure:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 17

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 18

The longest continuous carbon chain of carbon atoms contains five carbons and the parent name is PENT-1-ENE. The Suffix ‘1-ene’ represents the structure contains one double bond at C-1.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.26QP , additional homework tip 19

At each Carbon of 3 one phenyl group is present. Hence, the structure containing one substituent, then prefix ‘3-phenyl’ is added before the parent name. Hyphen separates the number that the substituent attached with carbon.

IUPAC name: 3-phenylpent-1-ene.