When HBr reacts with 1-butene, the product formed has to be predicted. Concept introduction: Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon. Markovnikov’s rule: In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

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Answer 1

Question

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

PROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= N

Which alkene is the major product of this dehydration? OH H2SO4 heat

Answer 2

Question

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

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Answer 3

Question

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

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Answer 4

Question

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

Expert Solution & Answer

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Answer 5

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

Answer 6

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

Answer 7

Chapter 24, Problem 24.23QP

a)

Interpretation Introduction

Interpretation:

When HBrreacts with 1-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

Answer 8

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

Answer 9

b)

Interpretation Introduction

Interpretation:

When HBrreacts with 2-butene, the product formed has to be predicted.

Concept introduction:

Addition reaction: Alkene reacts with polar reagent across the double bond, addition of hydrogen (electrophile) to the least substituted carbon and nucleophile bonded to the most substituted carbon.

Markovnikov’s rule:

In the overall reaction, the hydrogen atom (electrophile) is bonded to least substituted carbon and nucleophile is bonded to the most substituted carbon. This is known as Markovnikov’s rule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24.2 - How many structural isomers are there in the...Ch. 24.2 - Prob. 2PE Ch. 24.2 - Prob. 3PE Ch. 24.2 - Prob. 4PE Ch. 24.2 - Prob. 1RCF Ch. 24.2 - For which of the following compounds are cis-trans...Ch. 24.3 - Prob. 1RCF Ch. 24.4 - Prob. 5PE Ch. 24.4 - Prob. 1RCF Ch. 24 - Prob. 24.1QP

Solution Summary: The author explains that when HBr reacts with 1-butene, the product formed has to be predicted.

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Chapter 24 Solutions