Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 23.8, Problem 7P
Interpretation Introduction

Interpretation:

The product formed in each of the given reactions is to be identified.

Concept Introduction:

In an electrophilic aromatic substitution, if the ring bears several substituents, then the orientation is controlled by the most activating substituent.

Phenols contain hydroxyl (OH) functional group attached to an aromatic ring. In the ring, the electron withdrawing groups (EWG) decrease the electron density, thereby stabilizing the phenoxide ion.

On the other hand, the electron donating groups (EDG) increase the electron density, thereby destabilizing the phenoxide ion.

Phenols undergo electrophilic aromatic substitution reaction due to the presence of the hydroxyl group that activates itself towards electrophilic substitution.

The hydroxyl group causes the resonance effect due to which the ortho and para positions of the phenol ring become electron rich.

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NAME: 1. Draw the major product of the following E2 reaction. Make sure you pay attention to REGIOCHEMISTRY and STEREOCHEMISTRY. To get credit for this question, you must EXPLAIN how you got your answer using STRUCTURES and WORDS. Br NaOCH3 acetone F2 reaction To get credit for this
3. Reactions! Fill in the information missing below. Make sure to pay attention to REGIOCHEMISTRY and STEREOCHEMISTRY. Br2 CH3OH + 4. Mechanism! Show the complete arrow pushing mechanism, including all steps and intermediates for the following reactions. To get credit for this, you MUST show how ALL bonds are broken and formed, using arrows to show the movement of electrons. H3O+ HO
Please provide a synthesis for the Ester using proponoic acid, thank you!
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