The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated. Concept introduction: Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement. Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group. The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of o r t h o - and p a r a - substituted products.

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Answer 1

Question

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

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Answer 2

Question

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

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Check out a sample textbook solution

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Answer 3

Question

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

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Answer 4

Question

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

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Answer 5

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

Answer 6

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

Answer 7

Chapter 23.8, Problem 6P

Interpretation Introduction

Interpretation:

The two products that are formed in the Fries rearrangement of phenyl benzoate are to be stated.

Concept introduction:

Aryl esters react with aluminium chloride and result in the formation of hydroxy aryl ketones. This type of reaction is known as Fries rearrangement.

Aluminium chloride acts as a Lewis acid and it reacts with oxygen atom of acyl group.

The acyl group of the phenol ester migrates to the aryl ring. This rearrangement results in the formation of ortho- and para- substituted products.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 23.1 - Prob. 1P Ch. 23.3 - Problem 23.2 One of the hydroxybenzoic acids is...Ch. 23.4 - Prob. 3P Ch. 23.5 - Prob. 4P Ch. 23.6 - Problem 23.5 The compound shown was required for...Ch. 23.8 - Prob. 6P Ch. 23.8 - Prob. 7P Ch. 23.9 - Prob. 8P Ch. 23.9 - Prob. 9P Ch. 23.10 - Prob. 10P

Solution Summary: The author explains the Fries rearrangement of phenyl benzoate in the presence of aluminum chloride.

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