Organic Chemistry, Third Edition Binder Ready Version
3rd Edition
ISBN: 9781119110453
Author: Klein
Publisher: WILEY
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Chapter 23.8, Problem 25ATS
Interpretation Introduction
Interpretation:
The product obtained for given intramolecular Heck coupling reaction should be identified.
Concept Introduction:
Heck reaction: It describes the coupling reaction between aryl, vinyl or benzyl halide and
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Concentration
Trial1
Concentration of iodide solution (mA)
255.8
Concentration of thiosulfate solution (mM)
47.0
Concentration of hydrogen peroxide solution (mM)
110.1
Temperature of iodide solution ('C)
25.0
Volume of iodide solution (1) used (mL)
10.0
Volume of thiosulfate solution (5:03) used (mL)
Volume of DI water used (mL)
Volume of hydrogen peroxide solution (H₂O₂) used (mL)
1.0
2.5
7.5
Time (s)
16.9
Dark blue
Observations
Initial concentration of iodide in reaction (mA)
Initial concentration of thiosulfate in reaction (mA)
Initial concentration of hydrogen peroxide in reaction (mA)
Initial Rate (mA's)
Draw the condensed or line-angle structure for an alkene with the formula C5H10.
Note: Avoid selecting cis-/trans- isomers in this exercise.
Draw two additional condensed or line-angle structures for alkenes with the formula C5H10.
Record the name of the isomers in Data Table 1.
Repeat steps for 2 cyclic isomers of C5H10
Explain why the following names of the structures are incorrect.
CH2CH3
CH3-C=CH-CH2-CH3
a. 2-ethyl-2-pentene
CH3
|
CH3-CH-CH2-CH=CH2
b. 2-methyl-4-pentene
Chapter 23 Solutions
Organic Chemistry, Third Edition Binder Ready Version
Ch. 23.1 - Identify which of the following reagents is...Ch. 23.2 - Prob. 2CCCh. 23.2 - Prob. 3CCCh. 23.2 - Prob. 4CCCh. 23.2 - Prob. 5CCCh. 23.2 - Prob. 6CCCh. 23.3 - Show how you would prepare 1-butylcyclopentene...Ch. 23.3 - Prob. 7PTSCh. 23.3 -
Using any two organohalides of your choice...Ch. 23.3 - Prob. 9ATS
Ch. 23.4 - Prob. 10CCCh. 23.4 - Prob. 11CCCh. 23.5 - Prob. 2LTSCh. 23.6 - Prob. 3LTSCh. 23.6 - Prob. 16PTSCh. 23.6 - Prob. 17PTSCh. 23.6 - Prob. 18ATSCh. 23.6 - Prob. 19ATSCh. 23.7 - Prob. 4LTSCh. 23.7 - Prob. 20PTSCh. 23.7 - Prob. 21PTSCh. 23.7 - Prob. 22ATSCh. 23.7 - Prob. 23ATSCh. 23.8 - Prob. 5LTSCh. 23.8 - Prob. 24PTSCh. 23.8 - Prob. 25ATSCh. 23.8 - Prob. 26ATSCh. 23.9 - Prob. 27CCCh. 23.9 - Prob. 28CCCh. 23.9 - Prob. 29CCCh. 23.9 - Prob. 6LTSCh. 23.9 - Prob. 30PTSCh. 23.9 - Prob. 31PTSCh. 23.9 - Prob. 32ATSCh. 23 - Prob. 33PPCh. 23 - Prob. 34PPCh. 23 - Prob. 35PPCh. 23 - Prob. 36PPCh. 23 - Prob. 37PPCh. 23 - Prob. 38PPCh. 23 - Prob. 39PPCh. 23 - Prob. 40PPCh. 23 - Prob. 41PPCh. 23 - Prob. 42PPCh. 23 - Prob. 43PPCh. 23 - Prob. 44PPCh. 23 - Prob. 45PPCh. 23 - Prob. 46PPCh. 23 - Using 1-pentene as your only source of carbon...Ch. 23 - Prob. 48PPCh. 23 - Prob. 49PPCh. 23 - Prob. 50PPCh. 23 - Prob. 51PPCh. 23 - Prob. 52PPCh. 23 - Prob. 53PPCh. 23 - Prob. 54PPCh. 23 - Prob. 55PPCh. 23 - Prob. 56PPCh. 23 - Prob. 57PPCh. 23 - Prob. 58PPCh. 23 - Prob. 59IPCh. 23 - Prob. 60IPCh. 23 - Prob. 61IPCh. 23 - Prob. 62IPCh. 23 - Prob. 64IPCh. 23 - Prob. 66IPCh. 23 - Prob. 68IPCh. 23 - Prob. 69IPCh. 23 - Prob. 70IPCh. 23 - Prob. 71CPCh. 23 - Prob. 72CPCh. 23 - Prob. 73CPCh. 23 - Prob. 74CPCh. 23 - Prob. 75CPCh. 23 - Prob. 76CP
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