Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 23, Problem 82AE
Interpretation Introduction
Interpretation:
A series of colors of given complexes is given. The color of each complex on the basis of spectrochemical series is to be determined.
Concept introduction: The complimentary color of the absorbed color from the visible light is the color of the compound.
Energy is inversely proportional to the wavelength.
To determine:
The color of the given complexes.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 23 Solutions
Chemistry: The Central Science (14th Edition)
Ch. 23.2 - Prob. 23.1.1PECh. 23.2 - Prob. 23.1.2PECh. 23.2 - Prob. 23.2.1PECh. 23.2 - Prob. 23.2.2PECh. 23.4 - What is the name of the compound [Rh(NH3)4Cl2]Cl ?...Ch. 23.4 - Prob. 23.3.2PECh. 23.4 - Prob. 23.4.1PECh. 23.4 - Prob. 23.4.2PECh. 23.4 - Which of the following complexes has an optical...Ch. 23.4 - Prob. 23.5.2PE
Ch. 23.5 - Prob. 23.6.1PECh. 23.5 - Prob. 23.6.2PECh. 23.6 - Prob. 23.7.1PECh. 23.6 - Prob. 23.7.2PECh. 23.6 - Prob. 23.8.1PECh. 23.6 - Prob. 23.8.2PECh. 23 - Prob. 1DECh. 23 - The three graphs below show the variation in...Ch. 23 - Prob. 2ECh. 23 - Prob. 3ECh. 23 - Prob. 4ECh. 23 - Prob. 5ECh. 23 - Prob. 6ECh. 23 - Prob. 7ECh. 23 - Prob. 8ECh. 23 - Prob. 9ECh. 23 - Prob. 10ECh. 23 - Prob. 11ECh. 23 - Prob. 12ECh. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Write out the ground-state electron configurations...Ch. 23 - Prob. 16ECh. 23 - Prob. 17ECh. 23 - Prob. 18ECh. 23 - Prob. 19ECh. 23 - Prob. 20ECh. 23 - Prob. 21ECh. 23 - Prob. 22ECh. 23 - Prob. 23ECh. 23 - Prob. 24ECh. 23 - Prob. 25ECh. 23 - Indicate the coordination number and the oxidation...Ch. 23 - Prob. 27ECh. 23 - Prob. 28ECh. 23 - Prob. 29ECh. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - Prob. 32ECh. 23 - Prob. 33ECh. 23 - Prob. 34ECh. 23 - Write the formula for each of the following...Ch. 23 - Prob. 36ECh. 23 - Prob. 37ECh. 23 - Prob. 38ECh. 23 - Prob. 39ECh. 23 - Prob. 40ECh. 23 - Prob. 41ECh. 23 - Prob. 42ECh. 23 - Prob. 43ECh. 23 - Prob. 44ECh. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - Prob. 48ECh. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - 23.53
Sketch a diagram that shows the definition...Ch. 23 - Prob. 54ECh. 23 - Prob. 55ECh. 23 - Prob. 56ECh. 23 - Prob. 57ECh. 23 - Prob. 58ECh. 23 - Prob. 59ECh. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - 23.62 For each of the following metals, write the...Ch. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65ECh. 23 - Prob. 66ECh. 23 - Prob. 67AECh. 23 - Prob. 68AECh. 23 - Prob. 69AECh. 23 - Prob. 70AECh. 23 - Prob. 71AECh. 23 - Prob. 72AECh. 23 - Prob. 73AECh. 23 - Prob. 74AECh. 23 - Prob. 75AECh. 23 - Prob. 76AECh. 23 - Prob. 77AECh. 23 - Prob. 78AECh. 23 - Prob. 79AECh. 23 - Prob. 80AECh. 23 - Prob. 81AECh. 23 - Prob. 82AECh. 23 - Oxyhemoglobin, with an O2 bound to iron, is a...Ch. 23 - Prob. 84AECh. 23 - Prob. 85AECh. 23 - Prob. 86AECh. 23 - Prob. 87AECh. 23 - Prob. 88AECh. 23 - Prob. 89AECh. 23 - Prob. 90AECh. 23 - Prob. 91AECh. 23 - Prob. 92IECh. 23 - Prob. 93IECh. 23 - Prob. 94IECh. 23 - Prob. 95IECh. 23 - Prob. 96IECh. 23 - Prob. 97IECh. 23 - Prob. 98IECh. 23 - Prob. 99IECh. 23 - Prob. 100IECh. 23 - Prob. 101IE
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