(a) Interpretation: The difference between synthetic and natural polymer needs to be explained. Concept introduction: A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers .

Question

1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+

Answer 1

Question

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

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1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+

3. Name this compound properly, including stereochemistry. H₂C H3C CH3 OH 4. Show the step(s) necessary to transform the compound on the left into the acid on the right. Bri CH2 5. Write in the product of this LiAlH4 Br H₂C OH

What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.

Answer 2

Question

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

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Answer 3

Question

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

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Answer 4

Question

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

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Answer 5

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

Answer 6

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Answer 7

Chapter 23, Problem 35QAP

Interpretation Introduction

(a)

Interpretation:

The difference between synthetic and natural polymer needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The difference between polyester and polyamide needs to be explained.

Concept introduction:

A polymer is a long chain consists of large number of monomer units. In a polymer, the monomers are linked to each other in a continuous or repetitive manner. These monomer units are linked to each other either through the formation of peptide linkage, glycosidic linkage or by removal of any moiety such as a water molecule. Polyvinyl chloride, Bakelite and polystyrene are some of the examples of the polymers.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The difference between alpha and beta glucose needs to be explained.

Concept introduction:

Glucose is the simplest carbohydrate with molecular formula C₆ H₁₂ O₆ . It is also known as aldohexose because it contains an aldehyde group and there are 6 carbon atoms in the molecule.

The hemiacetal form of the glucose exists in two forms that is alpha and beta depending on the position of 1 of the 4-hydroxyl groups in the cyclic ring.

Answer 12

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Answer 23

Ch. 23 - Prob. 1QAP Ch. 23 - Prob. 2QAP Ch. 23 - Prob. 3QAP Ch. 23 - Prob. 4QAP Ch. 23 - Prob. 5QAP Ch. 23 - Prob. 6QAP Ch. 23 - Prob. 7QAP Ch. 23 - Prob. 8QAP Ch. 23 - Prob. 9QAP Ch. 23 - Prob. 10QAP

Solution Summary: The author explains the difference between synthetic and natural polymers.

Chapter 23 Solutions