ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 23, Problem 34P
In addition to the reaction mentioned in Section 23.5. PLP can catalyze β-substitution reactions. Propose a mechanism for the following PLP-catalyzed β-substitution reaction:
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Zn(OH)2(s)
Zn(OH)+
Ksp = 3 X 10-16
B₁ = 1 x 104
Zn(OH)2(aq)
B₂ = 2 x 1010
Zn(OH)3
ẞ3-8 x 1013
Zn(OH)
B4-3 x 1015
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QUESTION 3 - 4 POINTS
Complete the equation that relates the rate of consumption of H+ and the rate of formation of Br2 for the given reaction.
5Br (aq) + BrO3 (aq) + 6H (aq) →3Br2(aq) + 3H2O(l)
• Your answers should be whole numbers or fractions without any decimal places.
Provide your answer below:
Search
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5
fn
40
*
00
99+
2
9
144
a
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Chapter 23 Solutions
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
Ch. 23.1 - Prob. 2PCh. 23.1 - Prob. 3PCh. 23.2 - How many conjugated double bonds are there in a....Ch. 23.2 - Instead of adding to the 4a position and...Ch. 23.2 - Prob. 7PCh. 23.3 - Prob. 8PCh. 23.3 - Acetolactate synthase is another TPP-requiring...Ch. 23.3 - Acetolactate synthase transfers the acyl group of...Ch. 23.3 - Prob. 12PCh. 23.5 - Which compound is more easily decarboxylated?
Ch. 23.5 - Prob. 14PCh. 23.5 - Explain why the ability of PLP to catalyze an...Ch. 23.5 - Explain why the ability of PLP to catalyze an...Ch. 23.5 - The enzyme that catalyzes the C C bond cleavage...Ch. 23.5 - Propose a mechanism for the ,-elimination reaction...Ch. 23.6 - Ethanolamine ammonia lyase, a coenzyme...Ch. 23.6 - Prob. 20PCh. 23.7 - How do the structure of tetrahydrofolate and...Ch. 23.7 - What is the source of the methyl group in...Ch. 23.8 - Thiols such as ethanethiol and propanethiol can be...Ch. 23 - How does the metal ion in carboxypeptidase A...Ch. 23 - Prob. 24PCh. 23 - Prob. 25PCh. 23 - For each of the following reactions, name both the...Ch. 23 - Prob. 27PCh. 23 - When transaminated, the three branched-chain amino...Ch. 23 - What acyl groups have we seen transferred by...Ch. 23 - Propose a mechanism for the following reaction:Ch. 23 - Draw the products of the following reaction, where...Ch. 23 - When UMP is dissolved in T2O, exchange of T for H...Ch. 23 - Dehydratase is a PLP-requiring enzyme that...Ch. 23 - In addition to the reaction mentioned in Section...Ch. 23 - PLP can catalyze both ,-elimination reactions...Ch. 23 - The glycine cleavage system is a group of four...Ch. 23 - Prob. 37PCh. 23 - FADH2 reduces , -unsaturated thioesters to...
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